SESSION: AdvancedMaterialsTuePM1-R8 |
8th Intl Symposium on New & Advanced Materials and Technologies for Energy, Environment, Health and Sustainable Development |
Tue. 22 Oct. 2024 / Room: Ariadni B | |
Session Chairs: Tetiana Prikhna; Fernand D. S. Marquis; Student Monitors: TBA |
Nanodispersed iron oxides (contained mainly magnetit) obtained by the electroerosion dispersion (EED) technology was used to produce developed by M. Monastyrov feed additive Nano-Fe+TM. The efficiency of feed premixe Nano-Fe+TM was studied for growing broiler chickens. The method of increasing the productivity of agricultural animals and birds is to introduce iron nanopowder into the feeding ration by spraying feed with a suspension of iron nanopowder with a particle size of 20-30 nm in doses of 0.08-0.1 mg/kg of live weight per day. At the poultry faсtory, Nano-Fe+TM (suspension of iron oxides in glycerin) was diluted in water at a rate of 10 ml/10 l. The solution was sprayed on the feed of the birds before feeding at a rate of 10 l/1 ton of feed. The following results were obtained when using Nano-Fe+TM: the live weight gain of chickens increased by 5÷17%; the growth rate of broilers increased by 10÷20%; the protection of poultry from diseases increased by 10÷20%; the effects of stress from vaccination, regrouping, etc. decreased.
SESSION: AdvancedMaterialsTuePM3-R8 |
8th Intl Symposium on New & Advanced Materials and Technologies for Energy, Environment, Health and Sustainable Development |
Tue. 22 Oct. 2024 / Room: Ariadni B | |
Session Chairs: Tetiana Prikhna; Amr Henni; Student Monitors: TBA |
Ultra-high temperature (UHTC) transition metal borides can be used for a wide range of mechanical applications - as components of military and commercial equipment operating in extreme conditions, for rocket propulsion, hypersonic flights, atmospheric reentry, protective coatings on graphite, for using in abrasive, erosive, corrosive and high-temperature environments, which requires materials with significantly improved physical properties. To UHTC belongs TaB2 which exhibits high melting point (3200 °C), hardness (24.5 GPa -25.6 GPa), fracture toughness (4.5 MPa m0.5), bending strength (555 MPa), excellent chemical stability, electrical (308×104 Ω-1×m-1) and thermal (0.160 -0.161 W×cm-1×K-1 at 300-1300 oC) conductivity, good corrosion resistance [1-5]. To increase the oxidation resistance and mechanical characteristics TaB2 can be modified by silicides [1]. In the present study we investigated modification of TaB2 by MoSi2, ZrSi2 and Si3N4 in the amount of 20-30 wt.% and its sintering process under hot pressing conditions (30 MPa, 1750-1950 oC) and high pressure (4.1 GPa) - high temperature (1800 oC) conditions. The highest Vickers hardness HV=31.5 GPa and fracture toughness K1C=6 MPa×m0.5 under P= 9.8 N load was obtained for the composite sintered at 30 MPа, 1750 °C, 20 min from TaB2+20 wt.% ZrSi2, the increase of amount of ZrSi2 up to 30 wt.% leads to further increase in K1C= 6.9 MPa×m0.5, but to the reduction of microhardness down to HV=23.5 GPa. The composite sintered under 30 GPa at 1950 °C for 40 min from TaB2+20 wt.% MoSi2 showed HV=28.2 GPa and K1C= 5.42 MPa×m0.5. TaB2+30 wt.% Si3N4 sintered at 4.1 GPa, 1800 oC for 7 min had HV=18.8 GPa and K1C= 4.82 MPa×m0.5. The specific weight of the materials prepared from TaB2+20 wt.% MoSi2 was g=10.82 g/cm3, TaB2+30 wt.% Si3N4 - g=8.77 g/cm3, TaB2+20 wt.% ZrSi2 - g=9.35 g/cm3, TaB2+30 wt.% ZrSi2 - g=10.12 g/cm3.
AcknowledgementS: This work was supported by the Project of the National Academy of Sciences of Ukraine III-5-23 (0786) “Study of regularities and optimization of sintering parameters of composite materials based on refractory borides and carbides, their physical and mechanical properties in order to obtain products of complex shape for high-temperature equipment with an operating temperature of up to 2000 oC”
SESSION: AdvancedMaterialsWedPM2-R8 |
8th Intl Symposium on New & Advanced Materials and Technologies for Energy, Environment, Health and Sustainable Development |
Wed. 23 Oct. 2024 / Room: Ariadni B | |
Session Chairs: Tetiana Prikhna; Fernand D. S. Marquis; Student Monitors: TBA |
REBCO (Re=Y, Eu, Gd) coated conductors (CC) based on biaxially textured, thick and homogeneous nanoengineered multilayer structures opened up new application opportunities, such as dissipation-free energy transmission in superconducting grids, highly efficient engines for electrical aviation or compact fusion reactors beyond ITER. However, current carrying capacities of CC could be further improved because they are still far from theoretical limits. As it has been shown, one of the possible robust ways to increase current carrying capacity of CC is overdoping with oxygen the REBCO structure of CC.
Treatment of GdBCO_CC under 100 bar of O2 at 600 °C for 3 h led to an increase in Jc (77K, 0 T) by 6% and a decrease in the c-parameter of Gd123 to 1.17310 nm, which may be associated not only with overdoping with oxygen, but also with silver diffusion into Gd123. No correlation was observed between Jc, Tc, c-parameter of RE123 (RE=Eu, Gd) and carrier density nH of EuBCO_CC and GdBCO_CC treated at 300-800 oC, 1-160 bar O2 for 3-12 h.
We have started investigating high oxygen pressure treatments of GdBCO and EuBCO-BHO Coated Conductors previously oxygenated with standard treatments. For our experiments we used commercially produced GdBCO and EuBCO-BHO coated conductors provided by Fujikura. The CC samples have been previously oxygenated with their standard process. For the high oxygen pressure post-treatment, GdBCO and EuBCO-BHO coated conductors with 2 mm Ag layer on the surface of GdBCO CC and without and with Ag layer on the surface of EuBCO-BHO CC were used. Therefore, before experiments the upper Cu layer (and in some cases the Ag layer) was chemically removed from CCs tapes. In the case of EuBCO-BHO_CCs the Ag upper layer was removed chemically as well, but for some experiments it was preserved as indicated. The architecture (from top) of the studied CCs was as follows: (1) FYSC : Ag (2μm)/ GdBCO (1.8μm)/ CeO2 (700 nm)/ MgO/ / Al2O3/Y2O3 /Hastelloy (75 μm); (2) FESC : EuBCO (2.5μm)+BHO Nanorods/ CeO2 (700 nm)/ /MgO/ Al2O3/Y2O3 / Hastelloy (50 μm); (3) Ag (2μm)/ EuBCO (2.5μm)+BHO Nanorods/ CeO2 (700 nm)MgO/ / Al2O3/Y2O3/ Hastelloy (50 μm).
A specially designed tube furnace was used for the oxygenation process. The oxygen pressure in the furnace varied from 1 to 160 bar, the temperature from 300 to 800 °C, and the heating rate was 5 ºC/min. After, a dwell of temperature for a certain time held at the required pressure was attained, and afterwards the heater was turned off.
Results on critical current density, superconducting transition temperature, charge carrier densities, c-lattice parameter and Auger, indicate that high oxygen pressures of 100 and 160 bar can be sustained by these materials when high temperatures are used and that this can be a route to overdope these Coated Conductors. Furthermore, we evidence that these post oxygen treatements should be done without Ag etching so that the REBCO material is not exposed to air during the high pressure treatments. Futher work is on-going to obtain the best conditions to increase the charge carrier concentration and consequently the criticial current density in a robust way.
AcknowledgementS: We acknowledge funds from MUGSUP, UCRAN20088 project from CSIC programme from the scientific cooperation with Ukraine, the Spanish Ministry of Science and Innovation and the European Regional Development Fund, MCIU/AEI/FEDER for SUPERENERTECH (PID2021-127297OB-C21), FUNFUTURE “Severo Ochoa” Program for Centers of Excellence in R&D (CEX2019-000917-S), and HTS-JOINTS (PDC2022-133208-I00), NAS of Ukraine Project III-7-24 (0788) Authors also thanks Fujikura for supplying the samples