ORALS

SESSION: AdvancedMaterialsMonAM-R10	6th Intl. Symp. on New & Advanced Materials & Technologies for Energy, Environment, Health & Sustainable Development
Mon. 28 Nov. 2022 / Room: Saitong
Session Chairs: Fernand Marquis; Session Monitor: TBA

11:55: [AdvancedMaterialsMonAM02] OS Plenary
STRUCTURE, PROPERTIES AND APPLICATION of MT-YBCO and bulk MgB2-BASED SUPERCONDUCTORS
Tetiana Prikhna¹ ; Michael Eisterer² ; Vladimir Sokolovskiy³ ; Viktor Moshchil⁴ ; Bernd Büchner⁵ ; Xavier Chaud⁶ ; Dmitriy Efremov⁵ ; Dirk Lindackers⁵ ; Fernand Marquis⁷ ; Semyon Ponomarov⁸ ; Vladimir Sverdun⁹ ; ¹V. Bakul Institute NASU, Kiev, Ukraine; ²Institute of Atomic and Subatomic Physics, TU Wien, Vienna, Austria, Vienna, Austria; ³Ben-Gurion University of the Negev, Beer-Sheva, Israel, Beer-Sheva 84105, Israel; ⁴Institute for Superhard Materials, Kiev, Ukraine; ⁵Leibniz-Institut für Festkörper- und Werkstoffforschung Dresden e. V., Dresden, Germany; ⁶Laboratoire National des Champs Magnétiques Intenses (LNCMI/CNRS), Grenoble, France; ⁷San Diego State University, San Diego, United States; ⁸Institute of Semiconductor Physics, Kiev, Ukraine; ⁹Institute for Superhard Materials of the National Academy of Sciences of Ukraine, Kiev, Ukraine;
Paper Id: 448 [Abstract]

A comprehensive investigation of the structural, superconducting and mechanical characteristics of MgB2-based bulk materials and melt-textured (MT) -YBCO, prepared under different pressure-temperature-time conditions, establishes correlations responsible for attaining high functional properties of the superconducting materials and fields of their effective application. The analysis of MgB2 and MT-YBCO from the point of view of their application in inductive fault current limiters and electrical machines showed the competientability of both MgB2 and MT-YBCO materials. The advantages and disadvantages of the both materials are discussed. A successful development of hydrogen as an energy carrier involves the transportation of liquid hydrogen over long distances. This would provide a widely available coolant for superconducting materials that operate efficiently at 20 K. Very promissing are MT-YBCO and MgB2-based materials. MT-YBCO can create higher magnetic fields but its preparation takes much longer and is rather complicated and expensive. Microcraking during oxygenation of the Y123 structure may lead to the appearance of hot sports during the operation of electrical devices. Oxygenation under high oxygen pressure and high temperature reduces the process duration and cracking hence leading to an increase of the critical current density and a reduction of the material anysotropy. The mechanical characteristics increase as well. The drawback of MgB2 ceramics can be its high sensitivity toward flux jumps, particularly reducing shield of AC magnetic fields. Manufacturing under high pressure results in dense MgB2 ceramics with a high mechanical perfomance. Both materials are promising for practical applications but futher reseach activity shoud be performed to undestand the mechanisms of their unique properties.

SESSION: AdvancedMaterialsMonAM-R10	6th Intl. Symp. on New & Advanced Materials & Technologies for Energy, Environment, Health & Sustainable Development
Mon. 28 Nov. 2022 / Room: Saitong
Session Chairs: Fernand Marquis; Session Monitor: TBA

12:45: [AdvancedMaterialsMonAM04] OS
Structure and mechanical characteristics of high pressure sintered ZrB2, HfB2 and ZrB2- TiB2, ZrB2-SiC composite materials.
Tetiana Prikhna¹ ; Anastasia Lokatkina² ; Viktor Moshchil³ ; Pavlo Barvitskiy³ ; Olexandr Borymskyi⁴ ; Florian Kongoli⁵ ; Fernand Marquis⁶ ; ¹V. Bakul Institute NASU, Kiev, Ukraine; ²Institute for Superhard Materials of the National Academy of Sciences of Ukraine, Kyiv, Ukraine; ³Institute for Superhard Materials, Kiev, Ukraine; ⁴V. Bakul Institute for Superhard Materials of the National Academy of Sciences of Ukraine, Kyiv, Ukraine; ⁵FLOGEN Technologies, Mont-Royal, Canada; ⁶San Diego State University, San Diego, United States;
Paper Id: 286 [Abstract]

The ZrB₂ and HfB₂ materials are promising for application in hypersonic aerospace, cutting tools, metallurgy, microelectronics and refractory industries. The structure and properties of sintered under high pressure (4GPa) - high temperature (1800 ^oC) or HP-HT conditions ZrB₂, HfB₂, ZrB₂+30%TiB₂ and ZrB₂-20% SiC refractory materials are under consideration. HP-HT sintered HfB₂ (a=0.3141, c=0.3473 nm γ=10.42 g/cm³) demonstrated hardness HV(9.8 N)=21.27±0.84 GPa, HV(49 N)=19.29±1.34 GPa, and HV(98 N)=19.17±0.5 GPa and fracture toughness K1C(9.8 N)=6.47 MN×m0.5. High pressure sintered ZrB₂ (a=0.3167 , c=0.3528 nm, γ=6.1 g/cm³) demonstrated HV(9.8N)= 17.66±0.60 GPa, HV(49 N)= 15.25±1.22 GPa, and HV(98 N)= 15.32±0.36 GPa and K1C(9.8 N)=3.64 MN×m0.5. Addition of 30 wt.% of TiB₂ to ZrB₂ did not allow to increase hardness of the material essentially (HV(9.8 N)=17.75±2.36 GPa, γ=5.29 g/cm³ ). Addition of 20 wt.% of SiC to ZrB₂ and sintering under high pressure allowed essential increase of hardness to HV(9.8 N)=24.18±0.7 GPa, HV(49 N)=16.68±0.5 GPa, and HV(98 N)=17.59±0.4 GPa and fracture toughness (K1C(9.8 N)=6.49 ± 0.25 MN×m^0.5, K1C(49 N)=7.06± 1.55 MN×m^0.5 , K1C(98 N)=6.18± 1.24 MN×m^0.5) of composite ZrB₂- SiC material (γ=5.03 g/cm³).

SESSION: AdvancedMaterialsMonPM1-R10	6th Intl. Symp. on New & Advanced Materials & Technologies for Energy, Environment, Health & Sustainable Development
Mon. 28 Nov. 2022 / Room: Saitong
Session Chairs: Tetiana Prikhna; Session Monitor: TBA

14:00: [AdvancedMaterialsMonPM105] OS
Aluminum dodecaboride - and boron carbide-based ceramics for extreme environments
Tetiana Prikhna¹ ; Pavlo Barvitskiy² ; Viktor Moshchil² ; Olena Prysiazhna³ ; Myroslav Karpets² ; Semyon Ponomaryov⁴ ; Volodymyr Kushch³ ; Valeriy Muratov⁵ ; Fernard Marquis⁶ ; ¹V. Bakul Institute NASU, Kiev, Ukraine; ²Institute for Superhard Materials, Kiev, Ukraine; ³Institute for Superhard Materials of the National Academy of Sciences of Ukraine, Kiev, Ukraine; ⁴Institute of Semiconductor Physics of the National Academy of Sciences of Ukraine (NASU), Kyiv, Ukraine; ⁵(1) Frantsevich Institute for Problems of Materials Science of the National Academy of Sciences of Ukraine, Kyiv, Ukraine; ⁶Naval Postgraduate School, Monterey, United States;
Paper Id: 285 [Abstract]

The developed lightweight dodecaboride - and boron carbide-based ceramic composites hold great potential for a wide range of applications in extreme conditions: personal protection or for armored defense of ground military equipment and vehicles for the manufacture of abrasive nozzles, friction pairs for pumping oil and other aggressive liquids, constructional ceramics for nuclear power plants, etc. The correlations between structures and mechanical characteristics of alpha-AlB¹²-, AlB₁₂C2-, B₄C-based lightweight ceramics and composites synthesized or sintered by hot pressing (at 30 MPa). The effect of C, TiC and SiC additions on the properties of the resultant composites and the particularities of the ceramics destruction under shock loading are discussed. Computer modeling of the influence of construction parameters of ceramic-composite barrier on ballistic steel rod of the B-32 armor-piercing bullet (hardness HRC = 67 and 5,32 g weight of the steel core) into a two-layer ceramic-composite barrier was performed. Ballistic tests performed on 10 mm thick plates fabricated from the developed ceramics showed that the materials could withstand shot using a bullet with initial kinetic energy of 3.7 kJ.

SESSION: AdvancedMaterialsMonPM2-R10	6th Intl. Symp. on New & Advanced Materials & Technologies for Energy, Environment, Health & Sustainable Development
Mon. 28 Nov. 2022 / Room: Saitong
Session Chairs: Stanislaw Pietrzyk; Session Monitor: TBA

16:20: [AdvancedMaterialsMonPM210] OS
Oxidation resistance of Ti-Al-C MAX phases-based bulk materials and coatings at high-temperatures
Tetiana Prikhna¹ ; Orest Ostash² ; Alexander Kuprin³ ; Viktoriya Podhurska⁴ ; Thierry Cabioc'h⁵ ; Tetiana Serbenyuk⁶ ; Viktor Moshchil⁷ ; Vladimir Sverdun⁶ ; Myroslav Karpets⁷ ; Semyon Ponomarov⁸ ; Alexandra Starostina⁶ ; Fernand D. S. Marquis⁹ ; Florian Kongoli¹⁰ ; ¹V. Bakul Institute NASU, Kiev, Ukraine; ²Karpenko Physical-Mechanical Institute of the National Academy of Sciences of Ukraine, Lviv, Ukraine; ³National Science Center Kharkov Institute of Physics and Technology, Kharkov, Ukraine; ⁴Physico-Mechanical Institute of the National Academy of Sciences of Ukraine, Lviv, Ukraine; ⁵Universite de Poitiers, CNRS/Laboratoire PHYMAT, Chasseneuil Futuroscope Cedex, France; ⁶Institute for Superhard Materials of the National Academy of Sciences of Ukraine, Kiev, Ukraine; ⁷Institute for Superhard Materials, Kiev, Ukraine; ⁸Institute of Semiconductor Physics, Kiev, Ukraine; ⁹United Nano technologies (UNT) and Integrated Materials Technologies and Systems (IMTS), Rapid City, United States; ¹⁰FLOGEN Technologies, Mont-Royal, Canada;
Paper Id: 284 [Abstract]

The, results of variations of structure in oxidizing atmosphere at high temperatures (after heating and thermocycling up to 600 – 1400 ^oC), and electrical conductivity (after long time heating at 600 ^oC) of MAX Ti₂AlC-, Ti₃AlC₂- and (Ti,Nb)₃AlC₂-based bulk materials with different porosity (prepared by synthesis in vacuum and/or by hot pressing) and coatings (vacuum-arc deposited) are presented. The characteristics of highly dense Ti-Al-C composite bulks and vacuum-arc deposited 6 m thick coatings before and after heating at 600 ^°C in air for 1000 h were compared. High electrical conductivity ((The, results of variations of structure in oxidizing atmosphere at high temperatures (after heating and thermocycling up to 600 – 1400 ^oC), and electrical conductivity (after long time heating at 600 ^oC) of MAX Ti₂AlC-, Ti₃AlC₂- and (Ti,Nb)₃AlC₂-based bulk materials with different porosity (prepared by synthesis in vacuum and/or by hot pressing) and coatings (vacuum-arc deposited) are presented. The characteristics of highly dense Ti-Al-C composite bulks and vacuum-arc deposited 6 &#181;m thick coatings before and after heating at 600 °C in air for 1000 h were compared. High electrical conductivity (<i>delta</i> m/S =1.3•10⁶ S/m) of the highly resistant toward oxidation (<i>delta</i> m/S=0.07 mg/cm²) Ti-Al-C coating was preserved after long-term heating in air. It was found that the specimen surface layers of MAX-phases Ti₃AlC₂ and Ti₂AlC based bulks and chromium-containing Crofer 22APU steel became semiconductors because of high-temperature long-term oxidation (at 600 ^°C). The vacuum-arc deposited Ti-Al-C coating revealed high oxidation resistance and electrical conductivity along with good mechanical characteristics, namely nanohardness H (10 mN)= 9.5±1.5 GPa, and Young’s modulus E=190±10 GPa, which make it very promising for interconnects of solid oxide fuel cells (SOFCs). Acknowledgements The investigations were performed in the frames of the project NATO SPS G5773 “Advanced Material Engineering to Address Emerging Security Challenges” for 2020-2023, the project 03-03-20 of Ukrainian-Belorussian cooperation for 2020-2021, and the projects III-3-20 (0779), III-5-19 (0778), and II-5-19 (ІНМ-29/20) supported by the National Academy of Sciences of Ukraine.