2024 - Sustainable Industrial Processing Summit
SIPS 2024 Volume 4. Kanatzidis Intl. Symp / Solid State Chemistry and Materials

Editors:F. Kongoli, M.A. Alario-Franco, I. Chung, M. Delferro, O. Farha, H. Kageyama, F. Marquis, A. Navrotsky, A. Tressaud, P. Trikalitis
Publisher:Flogen Star OUTREACH
Publication Year:2024
Pages:222 pages
ISBN:978-1-998384-10-5 (CD)
ISSN:2291-1227 (Metals and Materials Processing in a Clean Environment Series)
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    MULTISCALE CRYSTAL LATTICE CHEMISTRY FOR IMPROVING THERMOELECTRIC PERFORMANCE

    In Chung1;
    1SEOUL NATIONAL UNIVERSITY, Seoul, South Korea;
    Type of Paper: Invited
    Id Paper: 351
    Topic: 52

    Abstract:

    The introduction of foreign atoms or vacancies into crystal matrices forms atomic-level defects, giving rise to unique defect structures influenced by their coordination preferences and sizes relative to constituent atoms in the matrix. These defects can evolve into more complex structures like one-dimensional dislocations or nanostructures, each interacting uniquely with charge carriers and phonons, thereby significantly impacting the transport properties of bulk solids. Consequently, understanding the formation mechanisms of these defects is essential for developing highly predictable design principles and stabilizing desired defect structures within bulk crystals.

    In this presentation, I will discuss our recent research on the deliberate design of multiscale defect structures across various types of crystal lattices. These structures enable independent control over crucial physical parameters that determine the thermoelectric figure of merit (ZT), such as carrier mobility, concentration, electrical conductivity, and Seebeck coefficient. Through this approach, we explore unconventional pathways to enhance ZT, promising significant advancements in thermoelectric materials.

    Keywords:

    Thermoelectric; Design defects; Materials engineering

    Cite this article as:

    Chung I. (2024). MULTISCALE CRYSTAL LATTICE CHEMISTRY FOR IMPROVING THERMOELECTRIC PERFORMANCE. In F. Kongoli, M.A. Alario-Franco, I. Chung, M. Delferro, O. Farha, H. Kageyama, F. Marquis, A. Navrotsky, A. Tressaud, P. Trikalitis (Eds.), Sustainable Industrial Processing Summit Volume 4 Kanatzidis Intl. Symp / Solid State Chemistry and Materials (pp. 207-208). Montreal, Canada: FLOGEN Star Outreach