2023-Sustainable Industrial Processing Summit
SIPS2023 Volume 4. Echegoyen Intl. Symp / Nanomaterials for Future Energy Demands

Editors:F. Kongoli, M.P. Brzezinska, M.A. Alario-Franco, F. Marquis, M.S. Noufal, E.Palomares, J.M. Poblet, D.M. Guldi, A.A. Popov, A.R. Puente Santiago, B. Raveau, D. G. Rodriguez, S. Stevenson, T. Torres, A. Tressaud, M. de Campos
Publisher:Flogen Star OUTREACH
Publication Year:2023
Pages:166 pages
ISBN:978-1-989820-78-0 (CD)
ISSN:2291-1227 (Metals and Materials Processing in a Clean Environment Series)
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    BREAKING MOLECULES TO USE THEM BROKEN

    Juan Casado1;
    1UNIVERSITY OF MáLAGA, Málaga, Spain;
    Type of Paper: Regular
    Id Paper: 42
    Topic: 16

    Abstract:

    π-Organic diradicals are molecules with two unpaired electrons which emerge from the total or partial rupture of a chemical bond, typically a π-double bond.1 Such unpaired electrons are stabilized by delocalization over the π-system and, to some extent, remain chemically inert. This allows the possibility to exploit these new chemical species with broken bonds in organic electronic applications.2 In this contribution, we will describe the electronic structure of such organic diradical molecules and will address the key points that allow their implementation in organic field effect transistors devices,3 in photonics, in thermoelectric or thermopower applications.4

    Keywords:

    Electron; Energy; Photovoltaic; Spectroscopy; Diradicals, organic electronics

    References:

    1. J. Casado, Topic in Current Chemistry, 2017, 375, 73.
    2. Stephen Forrest, Organic electronics: Foundations and Applications, Oxford University press, 2020.
    3. S. Mori, S. Moles Quintero, N. Tabaka, R. KishI, R. González Núñez, A. Harbuzaru, R. Ponce Ortiz, J. Marín-Beloqui, S. Suzuki, C. Kitamura, C. J. Gómez-García, Y. Dai, F. Negri, M. Nakano, S. Kato, J. Casado, Angew. Chem. Int. Ed. 2022, 61, e202206680.
    4. D. Yuan, D. Huang, S. Medina Rivero, A. Carreras, C. Zhang, Y. Zou, X. Jiao, C. R. McNeill, X. Zhu, C. Di, D. Zhu, D. Casanova, J. Casado, CHEM, 2019, 5, 964-976.

    Cite this article as:

    Casado J. (2023). BREAKING MOLECULES TO USE THEM BROKEN. In F. Kongoli, M.P. Brzezinska, M.A. Alario-Franco, F. Marquis, M.S. Noufal, E.Palomares, J.M. Poblet, D.M. Guldi, A.A. Popov, A.R. Puente Santiago, B. Raveau, D. G. Rodriguez, S. Stevenson, T. Torres, A. Tressaud, M. de Campos (Eds.), Sustainable Industrial Processing Summit Volume 4 Echegoyen Intl. Symp / Nanomaterials for Future Energy Demands (pp. 143-144). Montreal, Canada: FLOGEN Star Outreach