2023-Sustainable Industrial Processing Summit
SIPS2023 Volume 14. Intl. Symp on Electrochemistry, Molten Salts, Corrosion and Recycling
| Editors: | F. Kongoli, R. Fehrmann, V. Papangelakis, I. Paspaliaris, G. Saevarsdottir, G. Kipouros, R. Singh, F. Wang, D. Macdonald, R. Gupta, M. Barinova, F. Ahmed, H. Ozgunay, K. Tang, N.N. Thanh, C. Gaidau, K. Kolomaznik |
| Publisher: | Flogen Star OUTREACH |
| Publication Year: | 2023 |
| Pages: | 114 pages |
| ISBN: | 978-1-989820-98-8 (CD) |
| ISSN: | 2291-1227 (Metals and Materials Processing in a Clean Environment Series) |
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UTILIZATION OF AS RECEIVED AND UNSW - DEVELOPED NEAR WHITENED FLY ASH IN VIRGIN WHITE POLYMER POLYPROPYLENE GENERATING BETTER MECHANICAL & IMPACT PROPERTIES
Sri Bandy1;1UNIVERSITY OF NEW SOUTH WALES, UNSW, SYDNEY AUSTRALIA, Sydney, Australia;
Type of Paper: Regular
Id Paper: 322
Topic: 66
Abstract:
Fly ash (FA) is a fine powder collected as residue in the exhaust gases from combustion chambers of pulverized coal fired boilers at thermal power plant stations. It is usually solid, irregularly spherical in shape; at times, it is a cenosphere with a hollow spherical shape. The size, chemical composition and the colour of fly ash vary depending on the coal type used in coal power stations.
Generally, fly ash particles are light to dark-grey in colour with sizes range up to several hundred microns. Fly ash normally consists of predominantly aluminium silicates with a range of other metal oxide being present. It has been used in several areas, such as cement and concrete applications, bricks, highway pavement, road bases, and backfills. In most countries, fly ash is usually under-utilized.
In this study, as received fly ash from Cement Australia owned coal-power furnaces and subsequently modified into near whitened fly ash (with 96 % whiteness of calcium carbonate) – a UNSW developed technology - were utilized as reinforcement in virgin white polymer polyethylene, using up to 50 weight wt. % of fly ash.
Results indicate that near whitened fly ash produces filled polypropylene composites visibly almost as white as the neat PP polymer. Also, tensile modulus and notched Charpy impact properties of the fly ash filled composites are substantially enhanced by the fly ash addition.
Scanning electron microscopy of notched impact fracture surfaces show smaller size fly ash particles are embedded in the interlamellar textural matrix of the polymer, thereby absorbing / transferring significant mechanical energy under impact.
Keywords:
Fly ash; composition; near whitened fly ash (NHFA); colour control; filler in polymers; properties of composites; tensile modulus; notched impact; crystalinity; mono-modal; bimodalReferences:
[1] A Zaeni, Sri Bandyopadhyay, C Sorrell, A Yu, J Rider, S Dain, C White, D Blackburn: Colour control in fly ash as combined function of particle size and chemical composition, Fuel, 89, 2, 2010, 399-404[2] Sri Bandyopadhyay, Akhmad Zaeni, Dilip Nath, Aibing Yu, Qinghua Zeng, Darryl Blackburn & Chris White : Advanced utilization of as received and near whitened fly ash in polypropylene polymer to improve mechanical, notched impact and whiteness colour properties International Journal of Plastics Technology volume 14, pages 51–56 (2010)