ORGANIC CHARGE TRANSPORTING-LAYERS IN PEROVSKITE SOLAR CELLS Juan Luis Delgado1; 1POLYMAT, Donostia-San Sebastian, Spain; PAPER: 77/Nanomaterials/Keynote (Oral) OS SCHEDULED: 15:55/Fri. 1 Dec. 2023/Dreams 3 ABSTRACT: In the present communication we will focus on the use of organic charge transporting materials that have synthesized in our lab and used to prepare Perovskite-based Solar Cells.1,2 In our research group we have dedicated a great effort on the preparation and study of novel organic compounds for their incorporation in perovskite solar devices, either as hole or electron-transporting layers. Thus, we have reported the use of fullerenes3,4 and NDIs5 as electron transporting layers in PSCs, to prepare efficient and stable devices. On the other hand we have prepared a great variety of hole transporting materials, including polymers,6 and Oligotryarylamine (OTA) functionalized with different cores such as HexaArylBenzene (HAB),7fullerene,8 or pillarene9 among others, to prepare highly efficient and stable in PSCs. References: 1) Pascual, J.; Delgado, J. L.; Tena-Zaera, R. J. Phys. Chem. Lett. 2018, 9, 28933; 2) S. F. Volker, S. Collavini, J. L. Delgado, ChemSusChem 2015, 8, 3012. 3) Collavini, S.; Kosta, I.; Völker, S. F.; Cabanero, G.; Grande, H. J.; Tena-Zaera, R.; Delgado, J. L. ChemSusChem 2016, 9, 1263; 4) Pascual, J.; Kosta, I.; Ngo, T. T.; Chuvilin, A.; Cabanero, G.; Grande, H. J.; Barea, E. M.; Mora-Seró, I.; Delgado, J. L.; Tena-Zaera, R. ChemSusChem VIP 2016, 9, 2679; 5) S. Valero, A. Cabrera-Espinoza, S. Collavini, J. Pascual, N. Marinova, I. Kosta, J. L. Delgado, Eur. J. Org. Chem. 2020, 5329; 6) S. Valero, S. Collavini, S. F. Völker, M. Saliba, W. R. Tress, S. M. Zakeeruddin, M. Grätzel, and J. L. Delgado, Macromolecules, 2019, 52, 2243; 7) M. Shasti, S. F. Völker, S. Collavini, S. Valero, F. Ruipérez, A. Mortezaali, S. M. Zakeeruddin, M. Grätzel, A. Hagfeldt, J. L. Delgado, Org. Lett,. 2019 21, 3261; 8) S. F. Völker, M. Vallés-Pelarda, J. Pascual, S. Collavini, F. Ruiperez, E. Zuccatti, L. E. Hueso, R. Tena-Zaera, I. Mora-Seró and J. L. Delgado, Chem.–Eur. J., 2018, 24, 8524; 9) O.Bettucci, J. Pascual, S.-H. Turren-Cruz, A. Cabrera-Espinoza, W. Matsuda, S. F. Völker, H. Köbler, I. Nierengarten, G. Reginato, S. Collavini, S. Seki, J.-F. Nierengarten, A. Abate, J. L. Delgado, unpublished results. |