Abstract:
This paper presents an experimental study on the strength and suction evolution of cemented paste backfill (CPB) and CPB that contains blast furnace Slag (Slag-CPB) with different content of sulphate at early ages. CPB and Slag-CPB with 0, 5,000, 15,000 and 25,000 ppm sulphate content were prepared and cured at room temperature (20°C) for 1, 3, 7 and 28 days. Mechanical, hydraulic conductivity test and microstructural analyses were performed on the studied samples, suction and electrical conductivity of the samples were monitored. The results show that sulphate has a significant negatively effect on the early age strength and suction evolution of CPB and can lead to a positive or negative effect on Slag-CPB i.e., cause an increase or decrease in strength and acceleration or reduction in the amount and rate of self-desiccation. Inhibition of cement hydration and pozzolanic reaction, ettringite induced coarseness of pore structure and sulphate absorption by C-S-H are found as main reasons that affect CPB strength and suction evolution. This study has demonstrated that the effect of sulphate on the early strength and self-desiccation of CPB is an important factor for consideration in the designing of cost-effective, safe and durable CPB structures as well as using slag for reducing the mining cycle time in sulphide mines.
References:[1] Kesimal A, Ercikdi B, Yilmaz E. The effect of desliming by sedimentation on paste backfill performance. Minerals Engineering. 2003;16(10):1009-11. [2] Grice AG. Recent minefill developments in Australia. Minefill 2001: 7 th International Symposium on Mining with Backfill2001. p. 351-7. [3] Yilmaz E, Kesimal A, Ercikdi B. Strength development of paste backfill samples at long term using two different binders. Proceedings of the 8th symposium on mining with backfill2004. p. 281-5. [4] Fall M, Pokharel M. Coupled effects of sulphate and temperature on the strength development of cemented tailings backfills: Portland cement-paste backfill. Cement and Concrete Composites. 2010;32(10):819-28. [5] Pokharel M, Fall M. Combined influence of sulphate and temperature on the saturated hydraulic conductivity of hardened cemented paste backfill. Cement and Concrete Composites. 2013;38:21-8. [6] Fall M, Benzaazoua M, Saa E. Mix proportioning of underground cemented tailings backfill. Tunnelling and Underground space technology. 2008;23(1):80-90. [7] Abo‐El‐enein S, Ata A, Hassanien A. Kinetics and mechanism of slag cement hydration. Journal of Chemical Technology and Biotechnology. 1982;32(7‐12):939-45. [8] Ramlochan T, Zacarias P, Thomas M, Hooton R. The effect of pozzolans and slag on the expansion of mortars cured at elevated temperature: Part I: Expansive behaviour. Cement and Concrete Research. 2003;33(6):807-14. [9] Hou W-M, Chang P-K, Hwang C-L. A study on anticorrosion effect in high-performance concrete by the pozzolanic reaction of slag. Cement and Concrete Research. 2004;34(4):615-22. [10] Osborne G. Durability of Portland blast-furnace slag cement concrete. Cement and Concrete Composites. 1999;21(1):11-21. [11] Idorn GM, Roy DM. Factors affecting the durability of concrete and the benefits of using blast-furnace slag cement. Cement, concrete and aggregates. 1984;6(1):3-10. [12] Pal S, Mukherjee A, Pathak S. Investigation of hydraulic activity of ground granulated blast furnace slag in concrete. Cement and Concrete Research. 2003;33(9):1481-6. [13] Pokharel M, Fall M. Coupled Thermochemical Effects on the Strength Development of Slag-Paste Backfill Materials. Journal of Materials in Civil Engineering. 2011;23(5):511-25. [14] Grice T. Underground mining with backfill. Proceedings of the 2nd Annual Summit-Mine Tailings Disposal Systems. 1998:234-9. [15] Bloss M. Below ground disposal (mine backfill). Paste and Thichened Tailings: a guide, ed Jewell, Fourie and Lord, University of Western Australia. 2002:103-26. [16] Belem T, Benzaazoua M, Bussière B. Utilisation du remblai en pâte comme support de terrain. Partie I: De sa fabrication à sa mise en place sous terre. Après-mines 2003. 2003:5-7. [17] Sherwood P. Effect of sulfates on cement-and lime-stabilized soils. Highway Research Board Bulletin. 1962(353). [18] Fall M, Benzaazoua M. Modeling the effect of sulphate on strength development of paste backfill and binder mixture optimization. Cement and Concrete Research. 2005;35(2):301-14. [19] Ghirian A, Fall M. Coupled Behavior of Cemented Paste Backfill at Early Ages. Geotechnical and Geological Engineering. 2015:1-26. [20] Ghirian A, Fall M. Coupled thermo-hydro-mechanical–chemical behaviour of cemented paste backfill in column experiments. Part I: Physical, hydraulic and thermal processes and characteristics. Engineering Geology. 2013;164:195-207.
|