2019-Sustainable Industrial Processing Summit
SIPS2019 Volume 9: Tressaud Intl. Symp. / Solid State Chemistry for Applications and Sustainable Development
| Editors: | F. Kongoli, M.A. Alario Franco, J. Etourneau, S. Kalogirou, F.D.S. Marquis, R. Martins, K. Poeppelmeier, B. Raveau, Y. Shimakawa, M. Takano |
| Publisher: | Flogen Star OUTREACH |
| Publication Year: | 2019 |
| Pages: | 130 pages |
| ISBN: | 978-1-989820-08-7 |
| ISSN: | 2291-1227 (Metals and Materials Processing in a Clean Environment Series) |
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Fe2+/Fe3+: Couple, an Ideal Redox for Topochemical Reactions
Olivier MENTRE1;1UCCS, Villeneuve d'Ascq, France;
Type of Paper: Keynote
Id Paper: 315
Topic: 52
Abstract:
The possibility to modify inorganic oxides at moderate temperatures, under kinetic rather than thermodynamic control leads to metastable structural rearrangements with novel electronic partitions and original properties. In most cases, the abundant literature reports modifications of the anionic sub-array dealing with anionic vacancies, interstitials or anionic exchanges. However, intercalation or morerare exsolution cases show exotic cationic modifications towards original intercalated/depleted phases. The Fe2+/Fe3+ redox properties stand ideally for easy in-lab reactions. For instance, the controlled oxidation of the 2D-ising ferromagnetic BaFe2+2(PO4)2 into Fe-depleted BaFe2/3+2-x(PO4)2 (x<0.66) leads to a series of intermediate phases with full vacancy/Fe ordering and to nanometric Fe2)O3) [1]. On the opposite, playing redox chemistry in 2D-oxides such as the multiferroic, YbFe2.5+2O4 and Yb2Fe2.66+3O7, the metal content is maintained but re-organized during reduction/oxidation very similarly to the hexagonal YMn3+O3 system [2,3]. Generally, all transformed compounds require complex crystal-chemistry features with occurrence of supercells, modulated structures, and/or disordered intergrowths. The possibility to tune, in a controlled way, various pristine frameworks opens a wide field of investigation for tailor-made crystallographic architectures within the field of giant anion/cation-labile systems.
Keywords:
Advances in the synthesis routes; Design of materials for sustainable energy production;References:
[1] I.Blazquez Alcover. et al., Crystal Growth and Design, 15(2015) 4237-4247.[2] S. Nicoud et al., JACS, 139 (2017),17031-17043.
[3] H. Kabbour et al., Inorg. Chem, 56(2017), 8547-8553.