2019-Sustainable Industrial Processing Summit
SIPS2019 Volume 12: Energy Production and Secondary Batterie
| Editors: | F. Kongoli, H. Dodds, M. Mauntz, T. Turna, K. Aifantis, A. Fox, V. Kumar |
| Publisher: | Flogen Star OUTREACH |
| Publication Year: | 2019 |
| Pages: | 112 pages |
| ISBN: | 978-1-989820-11-7 |
| ISSN: | 2291-1227 (Metals and Materials Processing in a Clean Environment Series) |
CD shopping page
Non-carbon Matrix Sulfur Cathodes for High Volumetric Specific Energy Lithium-sulfur Batteries
Guoran Li1; Xueping Gao1;1NANKAI UNIVERSITY, Tianjin, China;
Type of Paper: Plenary
Id Paper: 440
Topic: 14
Abstract:
Lithium-sulfur battery is recognized as one of the most promising energy storage devices with high energy density, however, the application and commercialization are severely hindered by both the practical gravimetric and volumetric energy densities due to the low sulfur content and tap density with light-weight and nonpolar porous carbon materials as sulfur host.
Herein, we have developed some metal oxides and oxyhydroxides, i.g. NiCo2O4, NiFe2O4, and CoOOH, as carbon-free sulfur immobilizer to fabricate sulfur-based composite as cathode for lithium-sulfur battery. These non-carbon matrix materials for sulfur can accelerate the catalytic conversion kinetics of lithium polysulfides by strong chemical interaction, successfully alleviating the shuttle isuue and leading to a good cycle stability. The S/NiCo2O4 composite presents a high gravimetric capacity of 1125 mAh g-1-composite at 0.1C rate, and a low fading rate of 0.039% per cycle over 1500 cycles at 1C rate. In particular, the S/NiCo2O4 composite with the high tap density of 1.66 g cm-3 delivers a large volumetric capacity of 1867 mAh cm-3-composite, almost twice that of the conventional S/carbon composite. With ultrahigh sulfur content of 91.8 wt% and tap density of 1.26 g cm-3, the sulfur/CoOOH composite delivers high gravimetric capacity and volumetric capacity of 1199.4 mAh g-1-composite and 1511.3 mAh cm-3 at 0.1C rate, respectively. Meanwhile, the sulfur-based composite presents satisfactory cycle stability with a slow capacity decay rate of 0.09% per cycle within 500 cycles at 1C rate. The works provide a new strategy to realize the combination of gravimetric energy density, volumetric energy density and good electrochemical performance of lithium-sulfur battery.
Keywords:
Cathodes; Energy; Li-S; Materials; SecondaryBattery;References:
[1] Zhen-Yu Wang, Lu Wang, Sheng Liu, Guo-Ran Li, and Xue-Ping Gao,Adv. Funct. Mater. 2019, 1901051.[2] Ya-Tao Liu, Dian-Dian Han, Lu Wang, Guo-Ran Li, Sheng Liu, and Xue-Ping Gao, Adv. Energy Mater. 2019, 1803477.
[3] Ze Zhang, Di-Hua, Wu, Zhen Zhou, Guo-Ran Li, and Xue-Ping Gao, Sci. China Mater., 2019, 62,74.