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FRAY INTERNATIONAL SYMPOSIUM VOLUME 4: MATERIALS RECYCLING, SILICON FOR PHOTOVOLTAIC CELLS AND BORON & BORATES
TABLE OF
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Chairman/ Editor Foreword........................................................................................................lxvii
Professor Derek Fray - Biography.............................................................................................lxxix
Editor's Biography...................................................................................................................lxxxiii
Organizers.................................................................................................................................lxxxv
International Committees.......................................................................................................lxxxvii
Session Chairpersons...............................................................................................................lxxxix
Sponsors/Financial Supporters...................................................................................................xciii
Sponsors Logos..........................................................................................................................xcvii
Corporate Section :
SOMIKA, Société Minière du Katanga .................................................................................ciii
RHI..........................................................................................................................................cv
Oschatz GmbH....................................................................................................................cvii
Berzelius Metall...................................................................................................................cix
Umicore, Precious Metals Refining......................................................................................cx
FLOGEN® Technologies Inc..............................................................................................cxi
PLENARY
Sustainability - The Challenge of 21st Century-Reflections on the Role of Science and Technology.........3
Florian Kongoli
Examples of Synergy Leading to Innovations in Materials Science.............................................15
Derek Fray
Doing More with Less: The Competitive Advantage in the 21st Century (Speech).....................25
Janez Potocnik
Investment into R&D, use of Urban Mines and International Cooperation:
Elements of a Win-Win Strategy (Speech)....................................................................................27
Reinhard Butikofer
The Quest for Sustainable and Responsible Mining (Speech).......................................................29
Stephan Dion
Sustainability is not Wishful Thinking; It Lies in Our and Your Hands! (Speech).......................33
Stephan Vavrik
Mining and Sustainable Development: Oxymoron or Rx for a Bright Future?
(Abstract Only)..............................................................................................................................39
Manuel E. Ramos, Krishna Parameswaran
Growing Material Requirements and Tightening Material Availabilities and a Legislative
Environment Change The Dynamics for Recycling (Abstract Only)............................................41
Mark Cafferey
KGHM - Our Way to Sustainability (Abstract Only)....................................................................43
Wojciech Kędzia
Lead Smelting and Refining at Weser-Metall GmbH (Abstract Only).........................................45
Ulrich Kerney
Effective Management for Productivity Improvement at a Metallurgical Complex:
The Peñoles Case (Abstract Only).................................................................................................47
Javier Hernandez-Gallegos
Integrated Battery Recycling at Berzelius Metall GmbH, Germany - A Closed Loop!
(Abstract Only)..............................................................................................................................49
Hans-Peter Behrendt
Recent Developments in Iron-Making Technologies in Japan......................................................51
Takashi Miwa, Kiichiro Kurihara
A Strategy of Metal Resources for Sustainable Development and Supporting Technologies
for it in Japan (Abstract Only).......................................................................................................63
Takashi Nakamura
Charcoal Blast Furnace for Ironmaking (Abstract Only)..............................................................65
Jose Carlos D'Abreu, Cyro Takano
Materials Characterization of Complex Systems by Applying the Anomalous X-Ray
Scattering (Axs).............................................................................................................................67
Yoshio Waseda
Regenerative Energy System Using High-Temperature Electrolyzer and Fuel Cell
Equipped with Liquid Metal Electrodes........................................................................................81
K. T. Jacob
The Pivotal Role of Materials Science and Engineering in the Recycling of Materials
(Abstract Only)..............................................................................................................................97
Martin Pech-Canul, Florian Kongoli
Overview of Mineral and Metal Industry in Chile: Case of Copper Production (Abstract
Only)..............................................................................................................................................99
Mario Sanchez
Mining, Metallurgy, and Society (Abstract Only).......................................................................101
Fathi Habashi
SPECIAL ARTICLE
Changes of the Past 50 Years.......................................................................................................103
Derek Fray
VOLUME 4: MATERIALS RECYCLING, SILICON FOR PHOTOVOLTAIC CELLS AND BORON & BORATES
MATERIALS RECYCLING PROCESSES AND PRODUCTS
The Effect of Aluminum Chloride Additive on the Efficiency of Molten Salt Extraction
Process for Recovery of Chromium From Chromium Oxide......................................................109
Babak Khalaghi, Lidong Teng
"Urban Mining" at our Cities' Door Steps: Results of 2 Years of Renewable Phosphate
Fertilizer Production from Ash in a Pilot Plant...........................................................................119
Ludwig Hermann
Environmental Benefits Provided by the Recovery of Plastics from Shredding of
Automobiles.................................................................................................................................135
Daniel Froelich, Elisabeth Maris, Hugues De Feraudy,
Ingo Soppe, Wolfang Hang
Overview of The Vild-Project, Vanadium Recovery from BOF-Slag, a long
term Slag For The Swedish Steel Industry..................................................................................143
Guozhu Ye, Kim Kärsrud, Mikael Lindvall
Ni-Fe Alloy Prepared from Nonferrous Metallurgical Slag using Carbothermic
Electrochemical Reduction Method.............................................................................................155
Xingmin Guo, Changyu Sun
Accretion Formation in Zinc Oxide Calcination Kiln.................................................................165
P. Chris Pistorius, Gabriel L. Gerson, Regis J. Zagrocki
Urban Mining of MSWI Bottom Ashes (Keynote)......................................................................177
Peter C. Rem
E-Scrap Recycling System and Technologies in Japan (Abstract Only).....................................189
Takashi Nakamura
Polypropylene Recycling in Technology of Lead-Acid Battery Smelting
in Blast Furnace - 2-Year Experience(Invited).........................................................................................191
Zdenek Kunicky
Cyclam-Modified Electrodes for Lead Detection........................................................................197
Yingjun Liu, S. Vimalnath, S. Subramanian, S. Sampath,
Carsten Schwandt,R. Vasant Kumar
Microwave Assisted Recovery of Platinum (Abstract Only)......................................................207
T. Gerdes, Monika Willert-Porada
Recycling of Plastics from Post-Consumer Electronics: What's the Problem? (Keynote)
(Abstract Only)............................................................................................................................209
Maria Teresa Carvalho
Hardness and Impact Fracture Behavior of Polypropylene, Polystyreneand
Polyvinyl Chloride Blended With The Corresponding Recycled Material.................................211
Osvaldo. Barrera, Diana Marulanda, Marco Perez,
L.E. Parra,E. O. Inchima, Jose Luis Rubiano
Melting Behavior of Zinc Containing Residues(Keynote)..........................................................................217
Jürgen Antrekowitsch, Stefan Steinlechner
Investigations in the Improvement of Recycling of Electric Arc Furnace Dusts........................229
Stefan Steinlechner , Jürgen Antrekowitsch
Shredding Plant Configuration and its Performance: Improving the
Quality and Quantity of the Products for Sustainable Development...........................................241
Hamid-Reza Manouchehri
Closed Loop Recycling Process in TAB-MPI Group..................................................................263
Igor Lipovnik
Light Weight Lead Acid Batteries Towards Electrical and Hybrid Electrical Vehicle
Applications.................................................................................................................................267
Robert Liu, J Yang, Ramachandran Kumar
Metal Recovery from Industrial Solid Waste - Contribution to Resource Sustainability
(Abstract Only)............................................................................................................................273
Yongxiang Yang, Y. Xiao, R Boom
The Recycling of CRTs Glass by Thermal Processing................................................................275
Floriana La Marca
Addition of Borates and Resulting Microstructure of Stainless Steel Slags................................287
Yiannes Pontikes, Daneel Geysen, Lubica Kriskova,
Xuan Wang, Tom Jones, Bar t Blanpain
Salt Removal from Black Dross by Heat Treatment (Keynote)(Abstract Only).........................................299
Reza Khabazbeheshti, Ragnhild.E Aune, Seshadri Seetharaman
Physical and Chemical-Mineralogical Characterization of Fine Recycled
Aggregates from Construction and Demolition Waste................................................................301
Fernando Rodrigues, Maria Teresa Carvalho, Manuel Francisco Pereira,
Luís Evangelista, Jorge De Brito
Recovery of Packaging Glass from Mechanical Biological Treatment Reject...........................319
Maria Teresa Carvalho, Nilmara Dias
Possible Limits for Valorisation of the Slag Derived from the Smelting
of the Nickel Oxides in the Newco Ferronickel, Kosovo............................................................327
Musa Rizaj, Izet Ibrahimi, Nurten Deva, Shefik Imeri
Feronikel Slag Effect in Improvement Characteristics of Surface Layer Asphalet
Concrete.......................................................................................................................................335
Izet Ibrahimi, Musa Rizaj, Nurten Deva, Skender Sallahi
Recovery of Molybdenum by Carbothermic Reduction of Molybdenum
Bearing Spent Catalyst(Poster)...........................................................................................347
Biswabandita Kar
Sustainable Construction Materials from Clinker Free Cements Based
on Chemically Activated Ground Granulated Blast Furnace Slags(Poster).............................................353
Arjan Korpa, Kledi Xhaxhiu
Aluminum Foam Weight Opimization to Increase Absorption Energy in Melt Process(Poster)............373
Ali Akbar Mottahedi
Recycling of Waste Foundry Sand, Steel Slags and Bottom Ash in Cement Bound
Mixtures for Road Pavements(Poster)....................................................................................................381
Marco Pasetto, Nicola Baldo
Methodology for Recovery Precious Metals: Gold, Silver and Platinum Group
from Electronic Waste(Poster).................................................................................................................391
Oscar Jaime Restrepo, B. Honorio Oliveros Gómez
Zn Recovery from Zn-Fe Intermetallic Compounds Produced in Hot Dip
Galvanizing Process(Poster)... .............................................................................................399
Ricardo Sánchez, Federico Chávez Alcalá, Alejandro Cruz-Ramírez
Re-Use of Steel Slags in High Performance Asphalt Concretes for Road
Flexible Pavements(Poster)..... .....................................................................................413
Marco Pasetto, Nicola Baldo
Processing of Lithium-Bearing Wastes to Obtain Li2CO3(Poster).........................................................423
Jitka Jandová, Ján Kondás, LuboŠ Havlák, Petr Dvořák
Carbon Nanotube Ribbons Produced by Pyrolysis Using a Sustainable
Waste Material(Poster).... ...................................................................................... ...................................431
Dilip C. D. Nath, Veena Sahajwalla
The Capitalization of the Fine Ferrous Wastes through Unconventional
Proceedings Obtaining some Unconventional Energo-Technological Sources
used as Raw Materials at the Steel Elaboration(Poster)................................................................435
Corneliu Stanasila, Nicolae Constantin,Octavian Stanasila, Perparim Demi
Solidification and Stabilization of Metal Finishing Sludge (Poster) (Abstract Only)..............................449
Cemile Yerlikaya, Ali Oztürk, Halil Dertli, Hasancan Okutan
Innovative Devices, Software Tools and Integrated Software and Hardware
Architecture in Solid Waste Recycling (Poster)(Abstract Only).............................................................451
Giuseppe Bonifazi
Disposal of the Lead-Containing Wastes at IMN'S Division Legnica (Poster) (Abstract Only)..............453
Arkadiusz Szpakowski
Global Copper Scrap Market and its Drivers (Poster) (Abstract Only)....................................................455
Carlos Risopatron
Ecological Steel and Cast Iron Castings Production (Poster) (Abstract Only).........................................457
Alena Pribulova, Dana Baricova
Waste Not, Want Not (Poster) (Abstract Only) ......................................................................459
Paul Kruesi
Vanadium Extraction of Petroleum Combustion Residues, and Production
Ferro-Vanadium by Aluminothermic Reduction Method (Poster) (Abstract Only).................................461
Mahmood Mahmoodi
The Preparation of Steel-Slag Based Ceramic Materials and the Analysis of its
Characterization (Poster) (Abstract Only).......................................................................................463
Hao Bai
Sustainable Use of Waste Plastics in Metallurgy and Materials Processing
(Keynote) (Poster) (Abstract Only)............... ................................................................................465
Norbert Fraunholcz
Study of Fluid Flow in Magnesium Electrolytic Cell in the Kroll Process
(Poster) (Abstract Only)............................. ...............................................................................................467
Go-Gi Lee, Hyun-Na Bae, Seon-Hyo Kim
Fluid Flow of the Molten Magnesium Salt in the Electrolysis Process
(Poster) (Abstract Only)............... ............................................................................... ..............................469
Go-Gi Lee, Hyun-Na Bae, Seon-Hyo Kim
Effect of the Composition and Electrode Distance on the Electrolysis
(Poster) (Abstract Only)............................................................................................................................471
Miseon Choi, Go-Gi Lee, Changkyu Lee, Sungkoo Jo, Jaeyoung Jung
Recovery of Europium, Yttrium, Zinc and Indium from Electronic Scraps
(Poster) (Abstract Only)........................................................................................ ....................................473
Carlos Morais, Luciene Resende
Off-Line and On-Line Analysis and Recognition of Post-Consumer
Polyolefins (Pp-Pe), of Different Origin and Characteristics, by Innovative
Spectroscopic Sensing Techniques (Poster) (Abstract Only)........................................................ 475
Giuseppe Bonifazi
New Effective Treatment Techniques for MSWI Bottom Ashes -
Current Finnish Activities (Poster) (Abstract Only).................................................................................477
Tero Korhonen, Pekka Mörsky, Jutta Laine-Ylijoki, Tommi Kaartinen
Copper Slag Characterization for Reprocessing by Flotation
(Keynote) (Poster) (Abstract Only)................................................................................ ...........................................479
Zoran Markovic
Carbstone: Valorisation Technology for Fine Grained Mineral Slags and Co2
(Poster) (Abstract Only)................ ......................................................................... ..................................481
Mieke Quaghebeur, Ben Laenen, Peter Nielsen,
Evelyne Nguyen, Dirk Van Mechelen
The Use of Hyperspectral Imaging for New Sorting and Control Strategies
in Materials Recycling Processes(Poster)..................................................................................483
Silvia Serranti
Building Construction Materials(Poster)............................................................................ ......................485
Kenan Krasniqi
A Study on Production of Active Zinc Oxide by a Hydrometallurgical Process
(Poster) (Abstract Only)......................................................................... ..................................................487
Cem Colakoglu,, Onuralp Yücel
SILICON PRODUCTION, REFINING & RECYCLING FOR PHOTOVOLTAIC CELLS
Electrochemical Formation of Porous Silicon Layers in Molten Salt........................................491
Eimutis Juzeliunas, Antony Cox, Amr Abdelkader, Derek J. Fray
Correlation between Microstructure of Metallurgical Grade Silicon,
Alloying with Calcium and its Leaching Behavior.............................. .......................................497
Yulia V. Meteleva-Fischer, Yongxiang Yang, Rob Boom,
Bert Kraaijveld, Henk Kuntzel
Distribution of Boron between Molten Silicon and Calcium-Silicate Slags(Keynote)..............................507
Lars Klemet Jakobsson,Merete Tangstad
Behavior of Phosphorus during Slag Refining of Metallurgical Grade Silicon.........................513
Yulia V. Meteleva-Fischer, Yongxiang Yang, Rob Boom,
Bert Kraaijveld, Henk Kuntzel
Settling of SiC Particles in Molten Silicon (Keynote)................................................................523
Arjan Ciftja, Anne Kvithyld, Arne Petter Ratvik, Morten Onsoien
Recycling of Top-Cut Silicon Scrap by Filtration (Abstract Only)............................................533
Arjan Ciftja
Thermodynamics of Silicon Solid Solutions for Optimizing the
Low Temperature Refining of Silicon ........................................................................................535
Takeshi Yoshikawa, Kazuki Morita, Sakiko Kawanishi and Toshihiro Tanaka
Electrolysis Process for Preparation of Solar Grade Silicon by Electrorefining
Metallurgical Grade Silicon in Molten KCl-NaF (Poster) .................. ......................................................545
Xiangyu Zou, Hongwei Xie, Yuchun Zhai, Xiaochuan Lang, Pyong Hun Kim
Purification of Metallurgical-Grade Silicon to Solar-Grade Silicon by
Low-Temperature Liquating Crystallization Method..................................................................553
Lixin Zhao, Zhi Wang, Zhancheng Guo, Chengyi Li
Removal of Boron during Slag Refining in Molten Silicon for SoG-Si (Poster) (Abstract Only)...........561
Eun Jin Jung, Byung Moon Moon, Dong Joon Min
Removal of Phosphorous and Boron from Silicon by using Vacuum and Steam
Plasma Refining with Electromagnetic Induction Melting (Poster) (Abstract Only)...............................563
Byung Moon Moon, Gangjune Kim, Hyun Jin Koo, Tae U Yu
BORON & BORATES: EXTRACTION, PROCESSING & APPLICATIONS
Viscoelastic Contact Problems with Friction and Damage.........................................................567
Nicolae Pop, Constantin Ghita, Gabriel Badescu
Production of Boron Carbide (Keynote)......................................................................................577
G.S. Gupta And Sachin Kumar
Reciprocal Borate Systems Polyhedration................ ..................................................................587
Vasily Lutsyk, Vera Vorob'eva, Olga Sumkina
Discovery of Boron Segregation in Metallurgical Grade Silicon by Chemical and Physical Characterization.593
Chengyi Li, Xuzhong Gong, Li-Xin Zhao, Zhi Wang, Zhancheng Guo, Yonggang Wan
Modeling of Thermodynamic Properties of Binary Melts Containing Lead Oxide(Poster)....................605
Andrei L. Shilov, Valentina L. Stolyarova
Thermodynamic Properties and Vaporization Processes of Ternary Borosilicate
Melts Studied by High Temperature Mass Spectrometry (Poster) (Abstract Only).................................615
Valentina Stolyarova
Adaptation of the Lattice Theory of Associated Solutions to Oxide Melts
Modeling (Poster)(Abstract Only)............................................................................ ................................617
Andrei Shilov
Temperature Dependence of Thermal-Diffusion in Lithium-Borate Melt
According to Light Scattering Data(Poster) (Abstract Only)...................................................................619
Nikolai Bokov
Synthesis of Boron Containing Ceramic Powders by Self Propagating High
Temperature Synthesis (SHS) Process(Poster) (Abstract Only)..............................................................621
Onuralp Yücel
Effect on Addition of NaCl to Boron Carbide Powder Produced By SHS
Method (Poster) (Abstract Only)........................................................................... ................................... 623
Murat Alkan, Onuralp Yücel