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FRAY INTERNATIONAL SYMPOSIUM VOLUME 3: MOLTEN SALTS & IONIC LIQUIDS 2011
TABLE OF
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Chairman/ Editor Foreword........................................................................................................lxvii
Professor Derek Fray - Biography.............................................................................................lxxix
Editor's Biography...................................................................................................................lxxxiii
Organizers.................................................................................................................................lxxxv
International Committees.......................................................................................................lxxxvii
Session Chairpersons...............................................................................................................lxxxix
Sponsors/Financial Supporters...................................................................................................xciii
Sponsors Logos..........................................................................................................................xcvii
Corporate Section :
SOMIKA, Société Minière du Katanga ...............................................................................ciii
RHI..........................................................................................................................................cv
Oschatz GmbH....................................................................................................................cvii
Berzelius Metall...................................................................................................................cix
Umicore, Precious Metals Refining......................................................................................cx
FLOGEN® Technologies Inc..............................................................................................cxi
PLENARY
Sustainability - The Challenge of 21st Century-Reflections on the Role of Science and Technology.........3
Florian Kongoli
Examples of Synergy Leading to Innovations in Materials Science.............................................15
Derek Fray
Doing More with Less: The Competitive Advantage in the 21st Century (Speech).....................25
Janez Potocnik
Investment into R&D, use of Urban Mines and International Cooperation:
Elements of a Win-Win Strategy (Speech)....................................................................................27
Reinhard Butikofer
The Quest for Sustainable and Responsible Mining (Speech).......................................................29
Stephan Dion
Sustainability is not Wishful Thinking; It Lies in Our and Your Hands! (Speech).......................33
Stephan Vavrik
Mining and Sustainable Development: Oxymoron or Rx for a Bright Future?
(Abstract Only)..............................................................................................................................39
Manuel E. Ramos, Krishna Parameswaran
Growing Material Requirements and Tightening Material Availabilities and a Legislative
Environment Change The Dynamics for Recycling (Abstract Only)............................................41
Mark Cafferey
KGHM - Our Way to Sustainability (Abstract Only)....................................................................43
Wojciech Kędzia
Lead Smelting and Refining at Weser-Metall GmbH (Abstract Only).........................................45
Ulrich Kerney
Effective Management for Productivity Improvement at a Metallurgical Complex:
The Peñoles Case (Abstract Only).................................................................................................47
Javier Hernandez-Gallegos
Integrated Battery Recycling at Berzelius Metall GmbH, Germany - A Closed Loop!
(Abstract Only)..............................................................................................................................49
Hans-Peter Behrendt
Recent Developments in Iron-Making Technologies in Japan......................................................51
Takashi Miwa, Kiichiro Kurihara
A Strategy of Metal Resources for Sustainable Development and Supporting Technologies
for it in Japan (Abstract Only).......................................................................................................63
Takashi Nakamura
Charcoal Blast Furnace for Ironmaking (Abstract Only)..............................................................65
Jose Carlos D'Abreu, Cyro Takano
Materials Characterization of Complex Systems by Applying the Anomalous X-Ray
Scattering (Axs).............................................................................................................................67
Yoshio Waseda
Regenerative Energy System Using High-Temperature Electrolyzer and Fuel Cell
Equipped with Liquid Metal Electrodes........................................................................................81
K. T. Jacob
The Pivotal Role of Materials Science and Engineering in the Recycling of Materials
(Abstract Only)..............................................................................................................................97
Martin Pech-Canul, Florian Kongoli
Overview of Mineral and Metal Industry in Chile: Case of Copper Production (Abstract
Only)..............................................................................................................................................99
Mario Sanchez
Mining, Metallurgy, and Society (Abstract Only).......................................................................101
Fathi Habashi
SPECIAL ARTICLE
Changes of the Past 50 Years.......................................................................................................103
Derek Fray
VOLUME 3: MOLTEN SALTS & IONIC LIQUIDS 2011
Dendrite Free Electrochemical Deposition of Aluminum from Al Scrap Using Ionic Liquids
(Keynote).....................................................................................................................................109
Ramana Reddy And D. Pradhan
Novel Analysis Methods for Reactions in Molten Salts..............................................................119
Graeme A. Snook, Katherine Mcgregor, Paul J. Fraser, Michael A. Leist, Andrew J.
Urban, Mark J. Styles, Daniel P. Riley, Matthew R. Rowles, Nicola V.Y. Scarlett,
Ian C.Madsen
Solubility of ZrO2 in Molten Salt System...................................................................................135
Yongxiang Xiao, V. Laging, A. Van Sandwijk And Y. Yang
Actinides Recovery from a Molten Chloride Salt (Abstract Only).............................................141
Annabelle Laplace, Hubert Boussier, Eric Mendes, Jean-François Vigier
Production of Lithium from LiOH Using Molten Salt Electrolysis for the
Storage of Hydrogen through LiH...............................................................................................143
Yuzuru Sato, Osamu Takeda, Mingming Li
Separation and Recovery of Uranium from Next Generation Research
Reactor Fuel Via Molten Salt Electrorefining.............................................................................151
Steven Herrmann, Kevin Norbash, Dan Wachs
CMPO Functionalized Task Specific Ionic Liquid for Actinide and
Lanthanide Extraction..................................................................................................................165
Ali Ouadi, Emilie Jobin, Olga Klimchuk, Clotilde Gaillard, Isabelle Billard
Solvation and Complexation of Ions in Ionic Liquids: Spectroscopic
and Theoretical Studies (Abstract Only).....................................................................................171
Clotilde Gaillard
Direct Production of Tungsten Carbide Via the FFC - Cambridge Process...............................173
Diem-Hang Tran-Nguyen, Derek J. Fray
Molten Salts Composites for Thermal Storage in Steam Commercial Plants.............................181
Mila Hadjieva, Metodi Bozukov, Tsecka Tsacheva
Thermodynamic Properties of Trivalent Lanthanide and Actinide Ions
in Alkali Chloride and Alkaline Earth Chloride Mixtures (Abstract Only).................................191
Toshiyuki Fujii, Akihiro Uehara, Kazuhito Fukasawa, Takeshi Uda,
Takayuki Nagai, Nobuaki Sato, Hajimu Yamana
New Materials Created by using Molten Salt Media and by Controlling
Interfacial Phenomena (Abstract Only).......................................................................................193
George Kaptay
Direct Electrochemical Conversion of Metal Oxides to Metal by Molten
Salt Electrolysis: An Overview (Keynote)..................................................................................195
K.S. Mohandas
Influence of the Physico-Chemical Characteristics of Powder Compacted Metal Oxide
Cathodes on the Direct Electro-Deoxidation in Molten Calcium Chloride Medium..................219
K.S. Mohandas and Derek J. Fray
Studies on the Electrochemical Deoxidation of Uranium Dioxide in Molten Calcium
Chloride........................................................................................................................................239
K.S. Mohandas, N. Sanil, L. Shakila, D. Sri Maha Vishnu, K. Nagarajan
Galvanostatic Studies on the Electro-Deoxidation of Solid Titanium Dioxide in Molten
Calcium Chloride.........................................................................................................................253
K.S. Mohandas, L. Shakila, N. Sanil, D. Sri Maha Vishnu,K. Nagarajan
Synthesis and Application of Functionalized Ionic Liquids for Carbon Dioxide
Absorption....................................................................................................................................269
Carlos Carlesi, Danilo Carvajal, Christian Bidart, Rómel Jiménez,
Mauricio Flores, álex Berg
On the Preparation of TiAl Alloy by Direct Reduction of the Oxide Mixtures in Calcium
Chloride Melt...............................................................................................................................287
Prabhat K.Tripathy, Derek Fray
Physical Characterisation of CNTs Produced by Chronoamperometric Method in
MoltenLiCl(Keynote)...................................................................................................................................297
Aleksandar Dimitrov, Perica Paunovic, Ana Tomova And Anita Grozdanov
Acidity in Ionic Liquids...............................................................................................................307
Lynn M. Mihichuk, Gordon W. Driver, Keith E. Johnson
The Preparation of Nanoscale Carbon from Graphite Via Molten Salt
Electrolysis (Keynote).................................................................................................................317
Carsten Schwandt , Aleksandar T. Dimitrov , Ali R. Kamali, Derek J. Fray
Electrochemical Analysis of Direct Extraction of Silicon from Silica in
Molten Salts (Keynote) (Abstract Only)......................................................................................325
George Chen
Flue Gas Cleaning by Ionic Liquid Selective Gas Absorption (Abstract Only)..........................327
Rasmus Fehrmann
Production of Intermetallic Compound Powders through Sodium and
Hydrogen Reduction of Chloride(Keynote).................................................................................................329
Chao Du1, Na Wang, Jun Zhu, Shuqiang Jiao, Hongmin Zhu
Quinone-Based Redox Active Ionic Liquids...............................................................................337
Andrew P. Doherty, S. Pentlavalli, K. D. Murnaghan, Laura Diaconu
Electrochemistry of Ionic Liquids Containing Quinone Functionality using Cavity
Microrlectrode Arrays .................................................................................................................349
Elena Laura Diaconu, Andrew P. Doherty
Synthesis of Uranium Trichloride for the Pyrometallurgical Processing
of Used Nuclear Fuel...................................................................................................................359
Brian Westphal, J.C. Price, Robert Mariani
Nonplanar Tie-Lines Method to Determine the Quaternary Eutectic
Coordinates (Abstract Only)........................................................................................................367
Vasily Lutsyk
Reasons for the Errors in the Graphics of Salt System (Abstract Only)......................................369
Vasily Lutsyk
Crystallization of CaO.SiO2 in a CaO-Al2O3-SiO2 Melt: Computer
Simulations and in-situ Experiments...........................................................................................371
Jeroen Heulens, Bart Blanpain, Nele Moelans
Interactions of Ionic Liquids with Solutes, Particles and Surfaces: Insights
from Molecular Simulation and Experimental Thermodynamics (Abstract Only).....................379
Agilio Padua, Margarida Costa Gomes
Comparison of High Temperature Methods for the Investigation of Melting and
Crystallisation Behaviour of Mould Powders..............................................................................381
Nathalie Kölbl, Irmtraud Marschall, Harald Harmuth,
Bernd Buchberger, Jürgen Reiter
Thermochemical and Thermophysical Properties of Molten Salts/Slags:
From Experiment to Modelling (Keynote) (Abstract Only).........................................................................395
Patrick Masset
Thermodynamic Characterization of Molten Salts by Vapour Pressure (Keynote)....................397
Harald A. Øye
Molecular and Ionic Species in Saturated Vapour Over Molten Ytterbium Bromides...............413
Mikhail Butman, Dmitri Sergeev, Vladimir Motalov, Lev Kudin,
Leszek Rycerz, Marcelle Gaune-Escard
The Application of Mixed Molten Salts NaCl-CaCl2, KCl-NaCl and
KCl-NaCl-CaCl2 in the FFC Cambridge Process.......................................................................427
Cai Zzhuofei, Guo Zhancheng, Tang Huiqing, Zhang Zhimei
Electrochemistry of Rare-Earth Metals and Synthesis their Borides
in Halide Melts (Abstract Only)..................................................................................................439
Sergey Kuznetsov, Marcelle Gaune-Escard
Galvanic Coatings of Molybdenum and Tungsten Carbides from Oxide Melts:
Electrodeposition and Initial Stages ff Nucleation......................................................................441
Victor Malyshev, Dmytro Shakhnin, Angelina Gab, Marcelle Gaune-Escard
The Effect of Electrolysis Parameters on the Coating Composition and Properties during
Electrodeposition Of Tungsten Carbides And Zirconium Diborides .........................................459
Victor Malyshev, Dmytro Shakhnin, Angelina Gab, Marcelle Gaune-Escard
Thermodynamic and Transport Properties of DyBr3-KBr Binary System.................................467
Ida Chojnacka, Leszek Rycerz, Marcel le Gaune-Escard
Compound Formation in Lanthanide-Alkali Metal Halide Systems (Keynote)..........................475
Marcelle Gaune-Escard, Leszek Rycerz , Ewa Ingier-Stocka, Slobodan Gadzuric
Electrochemical and Diffusion Study of Multi-Component Lanthanides to
LiCl-KCl Eutectic........................................................................................................................489
B. Sarma, K.S. Raja, S.K. Mohanty, M. Misra
Electrolytes for Low Temperature Aluminum Electrolysis....................................................503
Alexander Dedyukhin, Alexander Redkin, Pavel Tinghaev, Yury Zaykov
Electroforming from Molten Salts: Industrial Applications (Poster) (Abstract Only)..............................509
Anatoliy Shchetkovskiy, Timothy Mckechnie, Alexander Smirnov
High Temperature Electrochemical Synthesis of Functional Materials
in Molten Salts (Poster) (Abstract Only)...................................................................................................511
Sergey Kuznetsov
Electrochemical Synthesis of Double Carbides of Tungsten and Molybdenum
Coatings from Tungstenate-Molybdate-Carbonate Melts on Metal and Nonmetallic
(Diamond) Surfaces(Poster) ....................................................................................................................513
Marina Adamokova, Hasbi Kushkhov, Fatima Kuchmezova, Ruzana Mamhegova
The Investigation of Stainless Steel Corrosion in Chloride Melts (Poster) (Abstract Only)....................517
Ilya Polovov, Alexader V. Abramov, Oleg I. Rebrin , Vladimir Volkovich,
Trevor Griffiths
The Methodology of Developing Rare Metals Electrorefining Technology
(Poster) (Abstract Only)............................................................................................................................519
Oleg I. Rebrin, Ilya Polovov , Vladimir Volkovich, Trevor Griffiths
Reactions between Ti3SixAl(1-X)C2 (X = 0 - 1) Solid Solutions and a Molten
Cryolite-AlF3-CaF2-Al2O3 Electrolyte(Poster) (Abstract Only)............................................................521
Xiao Yan, Ty Tran, Marshall Lanyon, Shou Sun
Application of Absorption Spectroscopy for Studying Behaviour of
Radioactive Elements in Molten Salts(Poster) (Abstract Only)...............................................................523
Vladimir Volkovich, Trevor Griffiths
Reducing the Volume of Radioactive Waste: Catalyst Enhanced
Molten Salt Oxidation is the Answer(Poster) (Abstract Only) ................................................................525
Trevor Griffiths, Vladimir Volkovich
Physical and Chemical Properties of Molten Salts Composed of Mixed
Nitrate/Nitrite Anions and Group I and II Cations (Poster) (Abstract Only)............................................527
Joseph Cordaro, Alan Kruizenga, Nathan Siegel, Robert Bradshaw, Brian Iverson
Factors Controlling the Synthesis and Stabilisation of Metallic Nanoparticles
Generated in-situ in Imidazolium Ionic Liquids (Poster) (Abstract Only)...............................................529
Catherine Santini, Paul Campbell, Gorka Salas
Photo-Influence for the Salts of Green-Fluorescence-Protein (GFP) Analogues
(Poster) (Abstract Only)............................................................................................................................531
Kuangsen Sung
Dissolution Rate of Steel Pack Aluminized in Mel Salt Na2SO4 at 884 Centigrades
Determinated by Electrochemical Technique(Poster)..............................................................................533
Baldemar M., A. Oropeza
Electrochemical Synthesis of Nanoparticles Hexaboride Neodymium and
Praseodymium from Chloride-Fluoride Melts(Poster)....................................................................539
Hasbi Kushkhov, Zalina Zhanikaeva, Stanislav Chuksin
The Electrochemical Corrosion of Nickel in Sodium Chloride-Sulfuric Acid Solutions
at Different Concentration Ratios using an Electrochemical Method(Poster)........................................547
Baldemar M., A. Oropeza
Compute of the Diffusion Coefficient to the Alloy Fe-Ni, using the Randles-Sevcik
Correlation, in Basic NaOH Solution Environment(Poster)............................................................551
Baldemar M., A. Oropeza, Martínez Claudia
Passivation Zone of Ni and NiFe Alloy before Breaking of Protection Film Acid
Environment H2SO4 Solutions(Poster)..............................................................................555
Baldemar M., A. Oropeza, Martínez Claudia
Ionic Liquids and Reactive Azeotropes: The Continuity of the Aprotic and Protic
Classes and their Relation to Molten Salts(Poster)....................................................................559
José Nuno Canongia Lopes, Luís Paulo N. Rebelo