Synthesis Of Tungsten Silicide From Halogenide Oxide Ionic Melts
Marina
Adamokova1; Hasbi
Kushkhov1; Ruzana
Mamhegova1;
1KABARDINO-BALKARIAN STATE UNIVERSITY, Nalchik, Russian Federation;
Type of Paper: Regular
Id Paper: 223
Topic: 13Abstract:
In the present work results of electrochemical synthesis of tungsten silicide in halide-oxide melts are given. Optimum conditions of carrying out electrosynthesis of WSi2 are found: structure of melts, electrolysis regime and electrolysis temperature. The principal possibility of synthesis of tungsten silicide by electrolysis halide oxide melts was found.
Keywords:
Carbon; Compounds; Nanomaterials; Refractory; Tungsten;
References:
[1] Adamokova M.N. Kuchmezova F.Y. Joint electroreduction of tungsten ions and silicon in ionic melts // Proceedings of the Kabardino-Balkarian state University.-2012-№ 5.- c. 5-8.
[2] Kushkhov H.B., Adamokova M.N. Electrodeposition of metal tungsten, molybdenum and their carbides from halide-oxide low-temperature melts // Russian Journal of Electrochemistry, 2007, Vol. 43, No. 9, pp. 1049-1059.
[3] Kushkhov H.B., Adamokova M.N., Kvashin V.A. Study of the influence of fluoride, fluorosilicon-, fluoroborate - and metaphosphate - ions on the electroreduction of fluoride complexes of tungsten chloride in the melt KCl-NaCl-CsCl // Melts, 2006, № 5, p. 60-69.Full Text:
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Adamokova M, Kushkhov H, Mamhegova R. Synthesis Of Tungsten Silicide From Halogenide Oxide Ionic Melts. In: Kongoli F, Gaune-Escard M, Turna T, Mauntz M, Dodds H.L., editors. Sustainable Industrial Processing Summit SIPS 2016 Volume 9: Molten Salts and Ionic Liquids, Energy Production. Volume 9. Montreal(Canada): FLOGEN Star Outreach. 2016. p. 161-166.