Selection Of Reductant For Lead Flash Smelting Processes
Viktor
Shumskiy1;
1VNIITSVETMET, Ust-Kamenogorsk, Kazakhstan;
Type of Paper: Plenary
Id Paper: 123
Topic: 6Abstract:
KIVCET was the only commercial process for lead flash smelting until 2010. In 2011, Chinese process LOFS (Lead Oxygen Flash Smelting) joined KIVCET. The layer of carbon material formed in the smelting shaft at the surface of the melt bath under the flares of charge-oxygen burners is used as the reduction reactor in both processes. Conventionally, screened fraction of coke fines is used as a carbon material for formation of the porous layer. The possibility of usage of other carbon-bearing materials is reviewed in this Paper.
Keywords:
Furnace; Lead; Non-Ferrous; Processing; Recovery; Smelting;
References:
[1] Chengyan Wang, et al., Development and Industrial Application of an Improved Lead Ox-ygen-Enriched Flash Smelting Process. Proceedings of the 5th International Symposium on High-Temperature Metallurgical Processing / TMS. San Diego, California, USA, 2014
[2] V.A. Shumskiy, Interconnection of Technical Organization and Technological Capabili-ties in Modern Lead Smelting Processes. Proceedings of the 2015 Sustainable Industrial Processing Summit / V. 5: Vanyukov International Symposium on Non-ferrous and KI-VCET, Antalya, Turkey, 04-09 October, 2015
[3] http://www.outotec.com/ImageVaultFiles/id_723/d_1/cf_2/OTE_Outotec_Flash_Smelting_technology_eng_web.PDF
[4] M.A. Lyamina, V.A. Shumskiy, Theory of Lead-bearing Raw Material Processing by KI-VCET Process, 2004, VNIItsvetmet, p. 209 (Russian original)
[5] S. Glasstone, K.J. Laidler, H. Eyring, The theory of rate processes: the kinetics of I chemi-cal reactions, viscosity, diffusion and electrochemical phenomena, 1941, McGraw Hill, p.611
[6] H. Eyring, S.H. Lin, S.M. Lin, Basic Chemical Kinetics, 1980, John Wiley & Sons, p.504
[7] A.P. Sychov, et al.: The Role of Reaction of Carbon Gasification at Reducing of Liquid Slags. Russian Metallurgy (Metally), 5 (1976), 20-25 (Russian original)
[8] A.P. Sychov, et al.: Mathematical Model of the Carbothermic Reduction of Lead and Zinc Silicate Melt. Russian Metallurgy (Metally), 4 (1977), 22-28 (Russian original)
[9] Yu.I. Sannikov, M.A. Lyamina, V.A. Shumskiy, Yu.A. Grinin: Reduction of PbO at the Coke Checker of KIVCET Unit. Russian Metallurgy (Metally), 6 (1997), 19-24 (Russian original)
[10] M.I. Temkin: Gradientless methods for determining the reaction rates. Kinetics and catalysis, 4 (1962), 509-517 (Russian original)
[11] V.V. Pomerantsev, et al., Basics of practical combustion theory, 1986, Leningrad, Energoatomizdat, p.312 (Russian original)
[12] M.A. Lyamina, To the question of reductant choice for KIVCET-process, VNIItsvetmet works, Ust-Kamenogorsk, 2004 (Russian original)
[13] M.A. Lyamina: The role of carbon materials reactivity in KIVCET-process. Com-plex use of mineral raw materials (CUMM), 1 (2001), 61-68 (Russian original)
[14] A.P. Sychov, I.P. Polyakov: Condition and perspectives of implementation the autogenous processes into lead production, Non-ferrous metals, 8 (1981), 9-12 (Russian original)
[15] A.P. Sychov, I.P. Polyakov, Yu.I. Sannikov: Improvement of KIVCET smelting of lead-zinc sulfide raw materials, Non-ferrous metals, 10 (1985), 36-39 (Russian original)
[16] M.C. Ohrenbach, Reaction surface in the heterogeneous combustion, 1973, Siberian depart-ment publish. Nayka, p.200 (Russian original)
[17] Red. S.G.Gerasimov, et al., Heat Engineering handbook, 1957, Moscow-Leningrad, Gosenergoizdat, p.728 (Russian original)
[18] V.A. Shumskiy, Physico-chemical characteristics and defining technological principles of the KIVCET-processing of oxidized lead-bearing materials. Doctoral dissertation. Ust-Kamenogorsk, 2006 (Russian original)Full Text:
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Shumskiy V. Selection Of Reductant For Lead Flash Smelting Processes. In: Kongoli F, Xueyi G, Shumskiy V, Kozlov P, Capiglia C, Silva AC, Turna T, editors. Sustainable Industrial Processing Summit SIPS 2016 Volume 8: Non-ferrous, Rotary Kiln, Ferro-alloys, Rare Earth, Coal. Volume 8. Montreal(Canada): FLOGEN Star Outreach. 2016. p. 55-70.