Calcified Transformation of Iron and Titanium in the Calcification - Carbonization Process for Alumina Production
Yanxiu
Wang1; Tingan
Zhang2; Lv
Guozhi2; Yimin
Fu1; Zhu
Xiaofeng2; Weiguang
Zhang1;
1NORTHEASTERN UNIVERSITY, Shenyang, China; 2NORTHEASTERN UNIVERSITY,CHINA, Shenyang, China;
Type of Paper: Regular
Id Paper: 96
Topic: 37Abstract:
With the continuous consumption of high quality bauxite, the high-iron and high-titanium bauxite which is more difficult to dispose has to be used for alumina production gradually. Iron and titanium are both disadvantageous factors in the Bayer process which may have some impact on the alumina production in the calcification-carbonization process, especially in the calcification process. In this paper, the calcified transformation of iron and titanium in the calcification-carbonization process was investigated separately. The experimental results show that the additive Fe(OH)3 converts to Fe-containing hydrogarnet with the increase of temperature. Fe(OH)3 reacts more readily than Fe2O3 and promote the conversion of Fe-containing hydrogarnet. The additive TiO2 firstly transform to Ca3TiSi2(Al2Si0.5Ti0.5)O14 and then CaTiO3 with the elevated temperatures.
References:
[1] Wang Q.X., Zhang K.R., Zhao J.W., and Ma H.L. Status problems and countermeasures of development and utilization of bauxite resources in China [J]. Conservation and Utilization of Mineral Resources, 2008, (5): 46-50.
[2] Mohammad Z., Esmaeil J., Mirsaleh M., et al. Mineralogical and sink-float studies of Jajarm low-grade bauxite [J]. International Journal of Minerals, Metallurgy and Materials, 2010, 17(3): 251-256.
[3] Vincenzo M. S., Renzo C. Bauxite red mud in the ceramic industry. Part 1: thermal behavior [J], Journal of European Ceramic Society, 2000, 20(3): 235-244.
[4] Zhang T.A., Lv G.Z., Zhang Z.,M., Liu Y., Dou Z.H., Zhao Q.Y. The disposal of middle-low grade bauxite and the recycle of aluminum by Calcification-Carbonization method: China, Patent, 201410181684.X [P]. (PCT/CN2014/082674)
[5] Zhang T.A., Lv G.Z., Liu Y., Dou Z.H., Zhao Q.Y., Niu L.P., and He J.C., A consumption method of Bayer red mud : China, Patent, ZL201110275030.X [P].
[6] Zhang T.A., Lv G.Z., Liu Y., Zhang Z.,M., Zhu X.,F., Dou Z.H. The recovery of aluminum and alkali with Calcification-Carbonization method in the process of Bayer red mud: China, Patent, 201410182601.9 [P].
[7] Zhang T.A., Lv G.Z., Liu Y., Dou Z.H., Zhang Z.,M., Zhao Q.Y., Niu L.P. Calcification conversion by adding ores in the process of alumina production: China, Patent, 201410183034.9 [P].
[8] Zhang T.A., Lv G.Z., Liu Y., Dou Z.H., Zhao Q.Y., Niu L.P., and He J.C., The Digestion of Alumina in Middle-low Bauxite based on Calcification–carbonization Conversion: China, Patent, 201110275013.6[P].
[9] Li X.B., Fu W.A.., Zhou Q.S., Liu G.H., and Peng Z.H. Reaction behavior and mechanism of anatase in digestion process of diasporic bauxite [J]. Transactions of Nonferrous Metals Society of China, 2010, 20(1): 142-146.
[10] Wang, Y.X., Zhang T.A., Zhu X.F., Zhang G.Q. Reaction behavior of anatase titanium oxide in high calcium system[J]. Journal of Northeastern University of China, 2015, 36: 517–520.
[11] Zhang T.A., Lv G.Z., Liu Y., Wang Y.X., Dou Z.H., Zhao Q.Y. Comprehensive utilization of valuable metallic elements in the iron-aluminum multi-metal intergrown ores : China, Patent, ZL201410179437.6[P].Full Text:
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Wang Y, Zhang T, Guozhi L, Fu Y, Xiaofeng Z, Zhang W. Calcified Transformation of Iron and Titanium in the Calcification - Carbonization Process for Alumina Production. In: Kongoli F, Feng N, Polyakov P, Gaune-Escard M, editors. Sustainable Industrial Processing Summit SIPS 2016 Volume 3: Oye Intl. Symp. / Ionic Liquid and Aluminum. Volume 3. Montreal(Canada): FLOGEN Star Outreach. 2016. p. 77-84.