Reduced Graphene Oxide Supported Palladium-Based Alloys for Hydrogen Evolution Reaction
Jose
Cardoso1; David
Cardoso1; Luis
Amaral1; Cesar
Sequeira1; Melike
Sevim2; Onder
Metin2; Tansel
Sener3; Diogo
Santos1;
1INSTITUTO SUPERIOR TECNICO, UNIVERSIDADE DE LISBOA, Lisbon, Portugal; 2ATATURK UNIVERSITY, Erzurum, Turkey; 3TUBITAK MARMARA RESEARCH CENTER ENERGY INSTITUTE, Gebze/Kocaeli, Turkey;
Type of Paper: Regular
Id Paper: 360
Topic: 21Abstract:
The world's economy, just like our own way of life, is completely dependent on the access to energy. With the health problems arising from the pollution resulting from the consumption of fossil fuels and the unavoidable issue of the depletion of the non-renewable resources needed for their production, finding new, clean, and efficient fuels is a priority. Hydrogen is a promising alternative to be used as an energy carrier as it is the lightest and most abundant element in the Universe. Moreover, hydrogen is an extremely clean fuel as the only waste produced from its consumption is water. One way to produce hydrogen is via water electrolysis, by splitting the water molecule into oxygen and hydrogen when applying a potential difference between two electrodes immersed in an aqueous electrolyte. The main drawback of this process is its capital and operation costs, since a high overpotential is necessary for the hydrogen evolution reaction (HER) to take place. In order to overcome this issue novel efficient electrocatalysts are required to improve the electrolysis performance. This work intends to study Pd alloys as cathode electrocatalysts, namely PdAu, PdFe and PdFeAg alloys supported on reduced graphene oxide (rGO). The prepared electrodes are submitted to linear scan voltammetry, chronoamperometry and chronopotentiometry studies to characterise their activity for HER in alkaline media. The activity of the tested electrodes towards water electrolysis was established based on the obtained data.
Keywords:
Batteries; Energy; Fuels; Hydrogen; Materials;
References:
[1] British Petroleum, BP Statistical Review of World Energy 2014; London, 2014.
[2] Höök, M.; Tang, C.: Depletion of fossil fuels and anthropogenic climate change — A review. Energy Policy, 52 (2013), 797-809.
[3] Mukhopadhyay, K.; Forssell, O.: An empirical investigation of air pollution from fossil fuel combustion and its impact on health in India during 1973–1974 to 1996–1997. Ecol. Econ., 55 (2005), 235-250.
[4] Feng, S.; Hu, H.; Huang, W.; Ho, C.; Li, R.; Tang, Z.: Projected climate regime shift under future global warming from multi-model, multi-scenario CMIP5 simulations. Global Planet. Change, 112 (2014), 41-52.
[5] Santos, D. M. F.; Sequeira, C. A. C.; Figueiredo, J. L.: Hydrogen production by alkaline water electrolysis. Quím. Nova, 36 (2013), 1176-1193.
[6] Xu, G.R.; Hui, J. J.; Huang, T.; Chen, Y.; Lee, J. M.: Platinum nanocuboids supported on reduced graphene oxide as efficient electrocatalyst for the hydrogen evolution reaction. J. Power Sources, 285 (2015), 393-399.
[7] Marini, S.; Salvi, P.; Nelli, P.; Pesenti, R.; Villa, M.; Berrettoni, M.; Zangari, G.; Kiros, Y.: Advanced alkaline water electrolysis. Electrochim. Acta, 82 (2012), 384-391.
[8] Sawyer, D. T.; Sobkowiak, A.; Roberts, J. L. Electrochemistry for Chemists; John Wiley & Sons, Inc.: Canada, 1995.
[9] Safizadeh, F.; Ghali, E.; Houlachi, G.: Electrocatalysis developments for hydrogen evolution reaction in alkaline solutions - A Review. Int. J. Hydrogen Energy, 40 (2015), 256-274.
[10] Zinola, C. F.; Martins, M. E.; Tejera, E. P.; Neves Jr., N. P.: Electrocatalysis: Fundamentals and Applications. International Journal of Electrochemistry, 2012 (2012), 1-2.
[11] Limpattayanate, S.; Hunson, M.: Electrocatalytic activity of Pt-Pd electrocatalysts for the oxygen reduction reaction in proton exchange membrane fuel cells: Effect of supports. Renew. Energy, 63 (2014), 205-211.
[12] Huang, Y. X.; Liu, X. W.; Sun, X. F.; Sheng, G. P.; Zhang, Y. Y.; Yan, G. M.; Wang, S. G.; Xu, A. W.; Yu, H. Q.: A new cathodic electrode deposit with palladium nanoparticles for cost-effective hydrogen production in a microbial electrolysis cell. Int. J. Hydrogen Energy, 36 (2011), 2773-2776.
[13] Shao, M.: Palladium-based electrocatalysts for hydrogen oxidation and oxygen reduction reactions. J. Power Sources, 196 (2011), 2433-2444.
[14] Pierozynski, B.; Mikolajczyk, T.; Turemko, M.; Czerwosz, E.; Kozlowski, M.: Hydrogen evolution reaction at Pd-modified carbon fibre in 0.1 M NaOH. Int. J. Hydrogen Energy, 40 (2015), 1795-1799.
[15] Green, T.; Britz, D.: Kinetics of the deuterium and hydrogen evolution reactions at palladium in alkaline solution. J. Electroanal. Chem., 412 (1996), 59-66.
[16] Maoka, T.; Enyo, M.: Overpotential decay transients and the reaction mechanism on the Pd-H2 electrode. Surf. Technol., 8 (1979), 441-450.
[17] Enyo, M.; Maoka, T.: The hydrogen electrode reaction mechanism on palladium and its relevance to hydrogen sorption. Surf. Technol., 4 (1976), 277-290.
[18] Smiljanic, M.; Srejic, I.; Grgur, B.; Rakoceviv, Z.; Strbac, S.: Catalysis of hydrogen evolution on different Pd/Au(1 1 1) nanostructures in alkaline solution. Electrochim. Acta, 88 (2013), 589-596.
[19] Oliveira, M. C.; Rego, R.; Fernandes, L. S.; Tavares, P. B.: Evaluation of the catalytic activity of Pd–Ag alloys on ethanol oxidation and oxygen reduction reactions in alkaline medium. J. Power Sources, 196 (2011), 6092-6098.
[20] Safavi, A.; Kazemi, S. H.; Kazemi, H.: Electrocatalytic behaviors of silver–palladium nanoalloys modified carbon ionic liquid electrode towards hydrogen evolution reaction. Fuel, 118 (2014), 156-162.
[21] Pan, Y.; Zhang, F.; Wu, K.; Lu, Z.; Chen, Y.; Zhou, Y.; Tang, Y.; Lu, T.: Carbon supported palladium-iron nanoparticles with uniform alloy structure as methanol-tolerant electrocatalyst for oxygen reduction reaction. Int. J. Hydrogen Energy, 37 (2012), 2993-3000.
[22] Han, B.; Xu, C.: Nanoporous PdFe alloy as highly active and durable electrocatalyst for oxygen reduction reaction. Int. J. Hydrogen Energy, 39 (2014), 18247-18255.
[23] Carmo, M.; Roepke, T.; Roth, C.; dos Santos, A. M.; Poco, J. G. R.; Linardi, M.: A novel electrocatalyst support with proton conductive properties for polymer electrolyte membrane fuel cell applications. J. Power Sources, 191 (2009), 330-337.
[24] Chandrasekaran, S.; Choi, W. M.; Chung, J. S.; Hur, S. H.; Kim, E. J.: 3D crumpled RGO-Co3O4 photocatalysts for UV-induced hydrogen evolution reaction. Mater. Lett., 136 (2014), 118-121.
[25] Zhang, S.; Metin, Ö.; Su, D.; Sun, S.: Monodisperse AgPd alloy nanoparticles and their superior catalysis for the dehydrogenation of formic acid. Angew. Chem. Int. Ed., 52 (2013), 3681-3684.
[26] Trasatti, S.; Petrii, O. A.: Real surface area measurements in electrochemistry. J. Electroanal. Chem., 327 (1992), 353-376.
[27] Domínguez-Crespo, M. A.; Torres-Huerta, A. M.; Brachetti-Sibaja, B.; Flores-Vela, A.: Electrochemical performance of Ni-RE (RE = rare earth) as electrode material for hydrogen evolution reaction in alkaline medium. Int. J. Hydrogen Energy, 36 (2011), 135-151.
[28] Sanetuntikul, J.; Hang, T.; Shanmugam, S.: Hollow nitrogen-doped carbon spheres as an efficient and durable electrocatalyst for oxygen reduction. Chem. Commun., 50 (2014), 9473-9476.
[29] Santos, D. M. F.; Amaral, L.; Sljukic, B.; Maccio, D.; Saccone, A.; Sequeira, C. A. C. Electrocatalytic activity of nickel-cerium alloys for hydrogen evolution in alkaline water electrolysis. J. Electrochem. Soc., 161 (2014), 386-390.
[30] Abbaspour, A.; Norouz-Sarvestani, F.: High electrocatalytic effect of Au-Pd alloy nanoparticles electrodeposited on microwave assisted sol-gel-derived carbon ceramic electrode for hydrogen evolution reaction. Int. J. Hydrogen Energy, 38 (2013), 1883-1891.
 Full Text:
Click here to access the Full TextCite this article as:
Cardoso J, Cardoso D, Amaral L, Sequeira C, Sevim M, Metin O, Sener T, Santos D. Reduced Graphene Oxide Supported Palladium-Based Alloys for Hydrogen Evolution Reaction. In: Kongoli F, Dubois JM, Gaudry E, Fournee V, Marquis F, editors. Sustainable Industrial Processing Summit SIPS 2015 Volume 9: Physics, Advanced Materials, Multifunctional Materials. Volume 9. Montreal(Canada): FLOGEN Star Outreach. 2015. p. 161-170.