Synthesis and Characterization of Boron Nitride Powders Produced under Concentrated Light
Lina
Sartinska1; Yeugen
Voynich1; Gennadiy
Frolov1; Olexander
Koval1; Izabella
Timofeeva1; Anatoly
Kasumov1; Tarik
Eren2; Esra
Altay2; Cesarius
Jastrebski3; Vitaly
Tinkov4;
1FRANTSEVICH INSTITUTE FOR PROBLEMS OF MATERIALS SCIENCE, NAS OF UKRAINE, Kyiv, Ukraine; 2YILDIZ TECHNICAL UNIVERSITY, CHEMISTRY DEPARTMENT, FACULTY OF ART & SCIENCES, Istanbul, Turkey; 3CEPHOMA CENTRE AT FACULTY OF PHYSICS WARSAW UNIVERSITY OF TECHNOLOGY, Warszawa, Poland; 4KURDYUMOV INSTITUTE FOR METAL PHYSICS OF NASU, Kiev, Ukraine;
Type of Paper: Regular
Id Paper: 196
Topic: 18Abstract:
Structural similarity of graphitic carbon and hexagonal BN (h-BN) initiated the intensive studies of BN nanostructures. However, the ionic origin of BN leads to electronic structure and properties of BN structures that significantly differ from that of carbon nanostructures. Therefore, the goal of this work is to synthesize and research the properties of boron nitride powders and BN powders with additives (Ta, Si, In, C, Ni) produced under effect of concentrated light in a flow of nitrogen in a xenon high-flux optical furnace. Scanning and transmission electron and optical microscopes demonstrated structures of new morphologies for the powders, which were formed. X-ray Diffraction study, Raman scattering, Fourier transform infrared (FT-IR) spectroscopy and electron diffraction study have confirmed a complicated structure and phase composition of the powders with a prevalence of the amorphous phases. The study of optical properties was carried out on spectrophotometer. It was demonstrated an effect of experimental conditions, surface modification and additives on phase composition, optical properties, morphology and structure formation. The gaseous model based on an evolution of the bubble was proposed for explanation of nanotubes formation. Burst of these bubbles may result in graphene-like structures formation.
Keywords: Light heating, Nanostructures
Keywords:
Ceramic; Nanocomposites; Nanoparticles; Nanopowder; Nanoscience; Nanotechnology; Nanotubes; Processing; Synthesis;
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Sartinska L, Voynich Y, Frolov G, Koval O, Timofeeva I, Kasumov A, Eren T, Altay E, Jastrebski C, Tinkov V. Synthesis and Characterization of Boron Nitride Powders Produced under Concentrated Light. In: Kongoli F, Pech-Canul M, Kalemtas A, Werheit H, editors. Sustainable Industrial Processing Summit SIPS 2015 Volume 8: Composite & Ceramic, Quasi-crystals and Nanomaterials. Volume 8. Montreal(Canada): FLOGEN Star Outreach. 2015. p. 197-210.