2015-Sustainable Industrial Processing Summit
SIPS 2015 Volume 3: Takano Intl. Symp. / Metals & Alloys Processing

Editors:Kongoli F, Noldin JH, Mourao MB, Tschiptschin AP, D'Abreu JC
Publisher:Flogen Star OUTREACH
Publication Year:2015
Pages:550 pages
ISBN:978-1-987820-26-3
ISSN:2291-1227 (Metals and Materials Processing in a Clean Environment Series)
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    Influence of the Binder on the Mechanical Properties and on the Reduction Process of the Chromite Self-Reducing Pellets

    Cyro Takano1; Adolfo Zambrano2; Marcelo Mourao1; Solon Tagusagawa1; Alberto Nogueira1;
    1UNIVERSITY OF SAO PAULO, Sao Paulo, Brazil; 2PONTIFICIA UNIVERSIDAD CATOLICA DEL PERU, Lima, Peru;
    Type of Paper: Regular
    Id Paper: 72
    Topic: 3

    Abstract:

    In this work, the influence of the binders on the mechanical properties at high temperatures and on the reduction process of the chromite self-reducing pellets were studied.
    Compression strength was evaluated at room temperature after submitting them to the temperatures of 1173, 1273, 1373, 1473 and 1573. Bentonite, hydrated lime, molasses, carboxymethyl cellulose (CMC) and sodium silicate were tested with different contents.
    Initially, all the materials (chromite, ferrosilicon, petroleum coke and binder) were characterized by chemical analysis and particle size. After this, the materials were agglomerated as 15 pellets (P1 to P15). The compression strength was measured for green pellets, during curing period for 28 days, after drying and after submitting at high temperatures profiles. Decrepitation tests were also done. After reduction experiments, at 1773K, the products obtained (slag and metal) were analyzed by SEM and EDS. The best performance was obtained by the pellet P15 (4% sodium silicate as binder): it reached a compression strength of 5 kg-f/pellet (dry pellet) and of 15 and 15.5 kg-f/pellet, after heat treatment at 1173 and 1273K, respectively. None of tested pellets presented decrepitation. The pellet P15 achieved unitary reaction fraction, after 10 minutes at 1773K. It was observed slag formation after 3.5 minutes, harming the reaction CO/Chromite.
    Keywords: Ferrochromium, Self-reduction, Self-reducing pellets, Chromite.

    Keywords:

    Composite; Pellets; Process;

    References:

    [1] M.C Mantovani. Comportamento a frio e a quente de pelotas auto-redutoras de residuo de aciaria elétrica. [Mestrado], São Paulo, Escola Politecnica, Universidade de São Paulo 1998.
    [2] E.S.Marcheze Resistencia mecanica a frio e crepitação em pelotas auto-redutoras. [Mestrado], São Paulo, Escola Politecnica, Universidade de São Paulo, 1994.
    [3] A.P.Zambrano, C.Takano, A.E.A.Nogueira, M.B. Mourao, S.T. Tagusagawa. The reduction of self-reducing chromite pellets at 1773K intrapellet gradients. International Journal of Research and Reviews in Applied Sciences. 2012;13(1): 330-339.
    [4] A.P.Zambrano, C.Takano, A.E.A.Nogueira, M.B. Mourao, S.T. Tagusagawa, Y. Iguchi. High Carbon Ferro-Chromium by Self-Reducing Process: Effects of Fe-Si and fluxing agent additions. ISIJ International. 2011; 51(8):1296-1300.
    [5] A.P.Zambrano, C.Takano, A.E.A.Nogueira, M.B. Mourao. High Carbon Ferro-Chromium by Self-Reducing Process: Fundamentals. Songklanakarin Journal of Science and Technology Research and Development. 2009; 31:433-439.
    [6] A.P.Zambrano, C.Takano, M.B. Mourao, S.T. Tagusagawa. High Carbon Ferro-Chromium by Self-Reducing Process. Journal of Iron and Steel Research International. 2009; 16:1342-1346.
    [7] A.P.Zambrano, C.Takano, A.E.A.Nogueira, M.B. Mourao, S.T. Tagusagawa, Y. Iguchi. Chromites Reduction Reaction Mechanism in Carbon-Chromites Composite Agglomerates at 1173K. ISIJ International, 2007; 47:1585-1589.

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    Cite this article as:

    Takano C, Zambrano A, Mourao M, Tagusagawa S, Nogueira A. Influence of the Binder on the Mechanical Properties and on the Reduction Process of the Chromite Self-Reducing Pellets. In: Kongoli F, Noldin JH, Mourao MB, Tschiptschin AP, D'Abreu JC, editors. Sustainable Industrial Processing Summit SIPS 2015 Volume 3: Takano Intl. Symp. / Metals & Alloys Processing. Volume 3. Montreal(Canada): FLOGEN Star Outreach. 2015. p. 113-122.