2015-Sustainable Industrial Processing Summit
SIPS 2015 Volume 3: Takano Intl. Symp. / Metals & Alloys Processing

Editors:Kongoli F, Noldin JH, Mourao MB, Tschiptschin AP, D'Abreu JC
Publisher:Flogen Star OUTREACH
Publication Year:2015
Pages:550 pages
ISBN:978-1-987820-26-3
ISSN:2291-1227 (Metals and Materials Processing in a Clean Environment Series)
CD-SIPS2015_Volume
< CD shopping page

    Rare-Earths: From the Extraction to the Application

    Marcos de Campos1; Jose Adilson de Castro1;
    1UFF - FEDERAL FLUMINENSE UNIVERSITY, Volta Redonda, Brazil;
    Type of Paper: Regular
    Id Paper: 186
    Topic: 3

    Abstract:

    In the present day, rare-earths relevance has increased. Market and applications of rare-earths are discussed in detail. Praseodymium, Neodymium, Dysprosium and Terbium are in high demand for magnet fabrication. High-Efficiency Wind turbines for energy production require a large amount of these elements. The Europium price has decreased recently. Europium is usually in high demand due to its use in TV and computer screens. However, the replacement from CFLB - compact fluorescent ligh bulbs - to LED light bulbs reduced the need of Europium. There is significant oversupply of Cerium. Research and development should focus on new Cerium applications. Lanthanum has large applications in catalysis and batteries. Rare-earths can be extracted as byproduct of existing mines, for example phosphat mines that produce fertilizers. Heavy rare-earths as Dy and Tb can be obtained as byproduct of tin mines. As the price of rare-earth concentrate is very low, research should focus on more economic methods for rare earth oxide separation.

    Keywords:

    Rare-Earths; Magnet; Applications

    References:

    [1] Rare earth elements: Not so rare after all. March/22/2015. http://www.cbsnews.com/videos/rare-earth-elements-not-so-rare-after-all/
    [2] Alicia Wallace. Molycorp To Provide Minerals For Siemens Wind Turbines. 04/15/2015. http://www.denverpost.com/business/ci_27917646/molycorp-provide-minerals-siemens-wind-turbines
    [3] http://www.frontierrareearths.com/rare-earth-prices/. August/01/2014.
    [4] Hongpo Shen, Chinese tighten supply of rare earths as Terbium and Dysprosium prices soar. February 16, 2015. http://investorintel.com/technology-metals-intel/chinese-tighten-supply-rare-earths-terbium-dysprosium-prices-soar/
    [5] http://www.info-re.com/index.php?/shop/article/1238.
    [6] Quanyin Tan, Jinhui Li, Xianlai Zeng, Rare Earth Elements Recovery from Waste Fluorescent Lamps: A Review . Critical Reviews in Environmental Science and Technology, 45 (2015), 749–776.
    [7] http://minerals.usgs.gov/minerals/pubs/commodity/rare_earths/mcs-2015-raree.pdf
    [8] Byproduct Metals and Rare-Earth Elements Used In the Production of Light-Emitting Diodes—Overview of Principal Sources of Supply and Material Requirements for Selected Markets pubs.usgs.gov/sir/2012/5215/pdf/sir2012-5215.pdf
    [9] Xiao Zhang , Wei Liu , George Z. Wei , Debasis Banerjee , Zhichao Hu , Jing Li. Systematic Approach in Designing Rare-Earth-Free Hybrid Semiconductor Phosphors for General Lighting Applications . J. Am. Chem. Soc., 136 (2014) 14230–14236.
    [10] Vale e Petrobras podem viabilizar terras-raras no Brasil. 24/04/2012. http://br.reuters.com/article/topnews/idbrspe83n0aj20120424?pagenumber=1&virtualbrandchannel=0
    [11] Nikki Gordon-Bloomfield. NiMH Batteries Could Yet Again Power Electric Cars Says BASF, Thanks to Ten-Fold Increase in Energy Density. March 4, 2015.
    [12] https://transportevolved.com/2015/03/04/nimh-batteries-could-yet-again-power-electric-cars-says-basf-thanks-to-ten-fold-increase-in-energy-density/
    [13] Tsuyoshi Sasaki, Yoshio Ukyo, Petr Novák. Memory effect in a lithium-ion battery. Nature Materials 12 (2013), 569–575 .
    [14] Yuxin Tang, Yanyan Zhang, Jiyang Deng, Jiaqi Wei, Hong Le Tam, Bevita Kallupalathinkal Chandran, Zhili Dong, Zhong Chen, Xiaodong Chen. Nanotubes: Mechanical Force-Driven Growth of Elongated Bending TiO2-based Nanotubular Materials for Ultrafast Rechargeable Lithium Ion Batteries. Advanced Materials, 26 (2014), 6046.
    [15] Shin-ichi Okuoka, Yoshiyuki Ogasawara, Yosuke Suga, Mitsuhiro Hibino, Tetsuichi Kudo, Hironobu Ono, Koji Yonehara, Yasutaka Sumida, Yuki Yamada, Atsuo Yamada, Masaharu Oshima, Eita Tochigi, Naoya Shibata, Yuichi Ikuhara, Noritaka Mizuno. A new sealed lithium-peroxide battery with a Co-doped Li2O cathode in a superconcentrated lithium bis(fluorosulfonyl)amide electrolyte. Scientific Reports 4 (2014), Article number: 5684
    [16] James D. Widmer, , Richard Martin, Mohammed Kimiabeigi. Electric Vehicle Traction Motors Without Rare Earth Magnets. Sustainable Materials and Technologies 3 (2015) 7–13.
    [17] http://www.teslamotors.com/blog/induction-versus-dc-brushless-motors
    [18] http://my.teslamotors.com/roadster/technology/motor
    [19] http://www.ise.fraunhofer.de/de/downloads/pdf-files/aktuelles/photovoltaics-report-in-englischer-sprache.pdf
    [20] Björn Nykvist, Måns Nilsson. Nature Climate Change 5 (2015), 329–332.
    [21] http://www.siemens.com/press/en/pressrelease/?press=/en/pressrelease/2015/windpower-renewables/pr2015030149wpen.htm&content[]=WP
    [22] Guilherme Gonçalves Sotelo, Daniel Henrique Nogueira Dias, Rubens de Andrade, Jr., Richard Magdalena Stephan. Tests on a Superconductor Linear Magnetic Bearing of a Full-Scale MagLev Vehicle. IEEE Transactions on Applied Superconductivity, 21 (2011), 1464
    [23] Guilherme Sotello, UFF, personal communication.
    [24] Patrick Zhang. Comprehensive Recovery and Sustainable Development of Phosphate Resources Procedia Engineering 83 (2014), 37–51.
    [25] http://usrareearths.com/images/USREposter-10012010draft.pdf
    [26] Sam Rosenblum , Elwin L. Mosier Mineralogy and occurrence of europium-rich dark monazite. USGS Professional Paper 1181, 1983. pubs.usgs.gov/pp/1181/report.pdf
    [27] http://www.ggg.gl/docs/ASX-announcements/GMEL_Company_Presentation_March_2015.pdf
    [28] http://www.tasmanmetals.com/i/pdf/TSM150121.pdf
    [29] D. Rodrigues, J. A. de Castro,. M. F. de Campos. Perspectives for Rare-Earth Magnets in Brazil. Proceedings of 23rd International Workshop on Rare Earth and Future Permanent Magnets and Their Applications REPM 2014, 2014, Annapolis, Maryland, USA. v. 1. p. 12-14
    [30] http://www.cetem.gov.br/286-ii-seminario-brasileiro-de-terras-raras-acontece-no-cetemem-novembro
    [31] http://meetingorganizer.copernicus.org/EGU2014/EGU2014-12709-1.pdf
    [32] Carlos Cordeiro Ribeiro. Geologia, geometalurgia, controles e gênese dos depósitos de fósforo, terras raras e titânio do complexo carbonatítico Catalão I , GO. Tese de Doutorado, UnB, 2008. http://oatd.org/oatd/record?record=oai%3Abce.unb.br%3A2667
    [33] http://www.marketwatch.com/story/canada-rare-earth-integrates-rare-earth-refineries-with-rare-earth-properties-a-corporate-update-2014-12-03-18173421
    [34] http://www.mineracaoserraverde.com.br/project.php
    [35] http://thiagolim4.wix.com/wmrport
    [36] http://www.ahkbrasilien.com.br/fileadmin/ahk_brasilien/portugiesische_seite/departamentos/Cooperacao_e_Desenvolvimento/Polo_Mineral_do_Amazonas.pdf
    [37] http://www.dnpm.gov.br/dnpm/sumarios/sumario-mineral-2014
    [38] Jacques Lucas,Pierre Lucas,Thierry Le Mercier,Alain Rollat,William G. Davenport. Rare Earths: Science, Technology, Production and Use. 2015. Elsevier, Amsterdam.
    [39] http://dossiers.inventaire.poitou-charentes.fr/le-patrimoine-industriel/notice.php?id=IA17000238
    [40] http://pdf.blucher.com.br/chemicalengineeringproceedings/cobeq2014/2058-16070-171290.pdf
    [41] J. A. de Castro, .D. Rodrigues, M. F. de Campos. From Neodymium Oxide to NdFeB Alloy: An Overview on the Reduction Methods. Proceedings of 23rd International Workshop on Rare Earth and Future Permanent Magnets and Their Applications REPM 2014, 2014, Annapolis, Maryland, USA. v. 1. p. 358-360
    [42] Xin Ling. Xu Guangxian: Father of Chinese rare earths chemistry. Bulletin of Chinese Academy of Sciences. 23 (2009) 98-102.
    [43] Jiangxue Liu and Jan C. Bongaerts Mine Planning and Equipment Selection Supply Chain of Rare Earth Elements (REEs). Proceedings of the 22nd MPES Conference, Dresden, Germany, 14th–19th October 2013, Ed. Carsten Drebenstedt Raj Singhal Editors Mine Planning and Equipment Selection, (Springer, Heildelberg, 2014), p. 1419.
    [44] tecnologiammm.com.br/files/v11n3/v11n3a12.pdf
    [45] http://www.abq.org.br/cbq/2014/trabalhos/9/6259-19473.html
    [46] D. Kennedy. In: StrategischeRohstoffe-Risikovorsorge. Springer Spektrum, Berlin, 2014, p 201-217.
    [47] José Adilson de Castro, Marcos Flavio de Campos Modeling The Neodymium Metallic Reduction From Molten Salts Materials Science Forum 802 (2014), 607-612.

    Full Text:

    Click here to access the Full Text

    Cite this article as:

    de Campos M and de Castro J. Rare-Earths: From the Extraction to the Application. In: Kongoli F, Noldin JH, Mourao MB, Tschiptschin AP, D'Abreu JC, editors. Sustainable Industrial Processing Summit SIPS 2015 Volume 3: Takano Intl. Symp. / Metals & Alloys Processing. Volume 3. Montreal(Canada): FLOGEN Star Outreach. 2015. p. 289-300.