2015-Sustainable Industrial Processing Summit
SIPS 2015 Volume 2: Gudenau Intl. Symp. / Iron and Steel Making
Editors: | Kongoli F, Kleinschmidt G, Pook H, Ohno K, Wu K |
Publisher: | Flogen Star OUTREACH |
Publication Year: | 2015 |
Pages: | 340 pages |
ISBN: | 978-1-987820-25-6 |
ISSN: | 2291-1227 (Metals and Materials Processing in a Clean Environment Series) |
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Carbothermic Reduction Kinetics of Sabzevar Manganese Ore
Bahram
Inanlou1; Nasser
Towhidi2; Reza
Ghasemzadeh3;
1DEPARTMENT OF MATERIALS ENGINEERING KARAJ ISLAMIC AZAD UNIVERSITY, Alborz, Iran (Islamic Republic of Iran); 2UNIVERSITY OF TEHRAN, Tehran, Iran (Islamic Republic of Iran); 3ISLAMIC AZAD UNIVERSITY, Karaj, Iran (Islamic Republic of Iran);
Type of Paper: Regular
Id Paper: 484
Topic: 2Abstract:
The kinetics of carbothermic reduction of Manganese ore from Sabzevar mine deposit have been established. The investigations showed that in the temperature range of 900-1000°c, Pyrolusite (MnO2) in the ore was reduced to Manganese Monoxide (MnO). X-Ray Diffraction Analysis of the as-mined ore samples confirmed the presence of Pyrolusite as the major phase in the Manganese ores. Pyrolusite has been reduced in the different temperatures by regenerative agent (Graphite 99.99%) to Bixbyte (Mn2O3), Hausmannite (Mn3O4) and Manganese Monoxide (MnO). Isothermal roasting at temperatures of 900°C and 1000°C with roasting retention times of 300s, 600s, 900s, 1200s, 1500s, 1800s and 2100s was performed, while the weight loss was monitored by using laboratory digital balance and the phases derived from samples (1200s and 2100s) at both temperatures (900 and 1000°C) were examined by using XRD analysis. Temperature and time had a significant influence on the reducibility of the ores.
Keywords:
CO2; Carbon; Gas; Manganese;
References:
[1] R.N. Sahoo, P.K. Naik and S.C. Da: Leaching of manganese ore using oxalic acid as reductant in sulphuric acid solution”, Hydrometallurgy, 62(2001), 157–163.
[2] M.N. El Hazek, T.A. Lasheen and A.S. Helal: “Reductive leaching of manganese from low grade Sinai ore in HCl using H2O2 as reductant”, Hydrometallurgy, 84(2006), 187–191.
[3] H. Su, Y. Wen, F. Wang, Y. Sun and Z. Tong: “Reductive leaching of manganese from low-grade manganese ore in H2SO4 using cane molasses as reductant”, Hydrometallurgy, 93 (2008), 136–139.
[4] H.H. Abd El-Gawad, M.M. Ahmed, N.A. El-Hussiny and M.E.H. Shalabi: “Reduction of low grade Egyptian manganese ore via hydrogen at 800˚C - 950˚C”, Open Access Library Journal, l (2014), 427.
[5] I.S. Çardakli: “Production of high carbon ferromanganese from a manganese ore located in Erzincan”, The Graduate School of Natural and Applied Sciences of Middle East Technical University, September (2010).
[6] Technical report from www.ngdir.com, (2006).
[7] Donald, D. Carr: “Industrial Mineral and rocks”, Society of Mining and Metallurgy and Exploration, (1994).
[8] Larry L. Berger, Trace mineral availability, from www.saltinstitute.org, (2006).
[9] K. Harries-Ress, Manganese, A Myriad of Minor Market, Industrial Mineral, 7 (1993).
[10] S.K. Tarby and W. O. Philbrook: “The rate and mechanism of the reduction of FeO and MnO from silicate and aluminate slags by carbon–saturated iron” Trans. AIME, 239(1967), 1005-1017.
[11] W.L. Daines and R.D. Pehlke: “Kinetics of manganese oxide reduction from basic slags by carbon dissolved in liquid iron”, Metallurgical Transactions, 2 (1971), 1203-1211.
[12] R.J. Pomfret and P. Grieveson: “Kinetics of fast initial stage of reduction of MnO from silicate slags by carbon in molten iron”, Ironmaking and Steelmaking, 5 (1978), 191-197.
[13] T.Shimoo, S. Ando and H. Kimura: “Rates of MnO reduction from silicate slags with solid carbon”, J. Japan Inst. Metals, 48 (1984), 922-929.
[14] K.Upadhya: “The kinetics and mechanism(s) of manganese oxide reduction from liquid slag by carbon dissolved
[15] in iron”, ISS Transactions, 7 (1986), 1-6.
[16] K.Xu, G. Jiang, W. Ding, L. Gu, S. Guo and B. Zhao: “The kinetics of reduction of MnO in molten slag with carbon saturated liquid iron”, ISIJ International, 33V (1993), 104-108.
[17] T.A.Skjervheim:”Kinetics and mechanisms for transfer of manganese and silicon from molten oxide to liquidmanganese metal”, Dr. Ing. Dissertation, NTH, Trondheim,Norway,(1994)
[18] M.Tangstad: “The high-carbon ferromanganese process – coke bed relations”, Dr. Ing. Dissertation, NTH, Trondheim, Norway, (1996).
[19] V. Olson, M. Tangstad and S.E. Olsen, “Reduction kinetics of MnO-saturated slags”, Proc. INFACON 8, The Chinese Society for Metals, Beijing, China, (1998) , 279-283.
[20] S.Q.Guo, G.C Jiang, J. L. Xu and K. DXu: “Kinetics of reduction of MnO in molten slag with carbon under saturated liquid iron”, J. Iron & Steel Res. Int., 7 (2000), 1-5.
[21] M.Yastreboff, O. Ostrovski and S. Ganguly: “Effect of gas composition on the carbothermic reduction of manganese oxide”, ISIJ Int., 43 (2003), 161-165.
[22] M.Kumar, S. Ranganathan and S.N. Sinha: “Kinetics of reduction of different manganese ores”, International Ferro-Alloys Congress (INFACON XI), (2007) 241-246.
[23] R.Kononov, O. Ostrovski and S. Ganguly: “Carbothermalsolid state reduction of manganese ores: 3. phase development”, ISIJ International, steel science, 49(2009), 1115–1122.Full Text:
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Inanlou B, Towhidi N, Ghasemzadeh R. Carbothermic Reduction Kinetics of Sabzevar Manganese Ore. In: Kongoli F, Kleinschmidt G, Pook H, Ohno K, Wu K, editors. Sustainable Industrial Processing Summit SIPS 2015 Volume 2: Gudenau Intl. Symp. / Iron and Steel Making. Volume 2. Montreal(Canada): FLOGEN Star Outreach. 2015. p. 323-330.