2015-Sustainable Industrial Processing Summit
SIPS 2015 Volume 11: Recycling & Environmental

Editors:Kongoli F, Havlik T, Pagnanelli F
Publisher:Flogen Star OUTREACH
Publication Year:2015
Pages:410 pages
ISBN:978-1-987820-34-8
ISSN:2291-1227 (Metals and Materials Processing in a Clean Environment Series)
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    Problems of Zirconium Dioxide Recovery from Concentrate and Tailings

    Natalia Tyushkova1;
    1MOSCOW INSTITUTE OF STEEL AND ALLOYS, Moscow, Russian Federation;
    Type of Paper: Regular
    Id Paper: 197
    Topic: 7

    Abstract:

    Global demand for zirconium dioxide is actively growing. It is connected with the increase of its consumption not only in ceramic industry but also in high-tech fields. This factor imposes additional requirements on purity in the process of zirconum dioxide cleaning from impurities of phosphorus, silicon, iron and aluminum. This article focuses on the problems of baddeleyite cleaning, which is natural zirconium dioxide. It comprises in kamaforite complex apatite-magnetite ores in alkaline ultrabasic massifs of the Kola Peninsula. This study offers a technological solution to the intensification of baddeleyite concentrate and various tailings deep cleaning. With the help of mathematical modeling, it was managed to confirm that the mechanical activation is effective for intensifying the process of baddeleyite sulfation in order to clean it of impurities. The use of calculated optimum modes allows to reduce such process parameters as temperature, duration of the process, sulfuric acid consumption and also to determine conditions of the outrunning extraction into the solution of scandium and the main impurities in comparison with zirconium dioxide.

    Keywords:

    zirconium dioxide; baddeleyite; tailing; intensification; deep cleaning; mechanical activation; the optimum mode

    References:

    [1] M. Kolenkova, M. Dorokhina, V. Shumenko, N.Safuanova: New domestically produced zirconium stuff and ways of its treatment, Series: The production of rare metals,(1980) 2, p 20 (The Institute of Information on Non Ferrous Metals: Moscow)
    [2] N. Tyushkova, M. Kolenkova and others: On forsterite interaction with hydrochloric acid, Colleges’ Proceedings, Non-ferrous Metallurgy 1984:5.
    [3] N. Tyushkova, M. Kolenkova and others: The receiving of technical zirconium oxide from waste, Preservation of the environment and utilization of valuable tailings in metallurgy. Proceedings of MISIS. 1984, pp. 23-43 (Moscow Institute of Steel and Alloys: Moscow).
    [4] N.Tyushkova, O. Kabanova, Y. Maksimov, M. Kolenkova, L. Rusinov: The construction of physical-chemical model of rare metallic concentrate’s interaction with hydrochloric acid, Colleges’ Proceedings, Non-ferrous Metallurgy, 1985:3
    [5] A. Zelikman, G. Voldman, A. Ermilov: The research of influence of mechanical activation on zircon’s decomposition by the caking with calcium carbonate MISIS proceedings, 1979, pp 30-35 (Moscow Institute of Steel and Alloys: Moscow).
    [6] N.Tyushkova, O. Kabanova, M. Ekhanin: Mathematical modeling of physical-chemical decomposition of baddeleyite concentrate by hydrochloric acid, Interdepartmental Collection, MFTI, 1987:5, pp 23-34 (Moscow Physical & Engineering Institute: Moscow).
    [7] N. Tyushkova, 2007. On mechanical activation of baddeleyite concentrate, 9th Congress of CIS countries on ore-dressing. Moscow, 28-30 March, 2007.Congress proceedings.Vol.11, pp 12-23 (Altex: Moscow)
    [8] N. Tyushkova: Study on intensification of baddeleyite’s concentrate deep cleaning by mechanical activation The XXIV International Mineral Processing Congress. 22-28/09/2008. Beijing. China. IBSN 978-7-03-022711-9 Beijing.
    [9] N. Tyushkova: Research of intensification of baddeleyite concentrate deep cleaning by mechanical activation. Energy-saving technologies in the steel industry V International Scientific Conference 2010 ", Moscow, NITU MISiS, pp.201-210, ISBN 978-5-87623-378-3

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    Cite this article as:

    Tyushkova N. Problems of Zirconium Dioxide Recovery from Concentrate and Tailings. In: Kongoli F, Havlik T, Pagnanelli F, editors. Sustainable Industrial Processing Summit SIPS 2015 Volume 11: Recycling & Environmental. Volume 11. Montreal(Canada): FLOGEN Star Outreach. 2015. p. 163-168.