2014-Sustainable Industrial Processing Summit
SIPS 2014 Volume 4: Recycling & Secondary Battery
| Editors: | Kongoli F |
| Publisher: | Flogen Star OUTREACH |
| Publication Year: | 2014 |
| Pages: | 498 pages |
| ISBN: | 978-1-987820-06-5 |
| ISSN: | 2291-1227 (Metals and Materials Processing in a Clean Environment Series) |
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3D mesostructured electrodes for high energy and power density primary and secondary batteries
Paul Braun1;1UNIVERSITY OF ILLINOIS AT URBANA-CHAMPAIGN, Urbana, United States;
Type of Paper: Invited
Id Paper: 294
Topic: 12
Abstract:
Through mesoscale design of a 3D current collector, high power density and high energy density primary and secondary (rechargeable) batteries were fabricated. At the most fundamental level, mesostructuring enables optimization of the trade-off between energy and power density in energy storage systems due to unavoidable ohmic and other losses that occur during charge or discharge. Of course, it is at fast charge and discharge, where these effects are most important. By efficient design of the ion and electron transport pathways, we and others have shown it is possible to significantly improve the power-energy relationship. We have found a particularly effective way to provide these pathways is to use a colloidal-based template to form a mesostructured 3D current collector. The electrochemically active material is then deposited on this current collector. Using this approach, Li-ion batteries which could be discharged at up to 300C with 75% capacity retention were formed. The combination of a high surface area and short solid-state diffusion lengths offers a number of unique opportunities for both high energy and high power chemistries. As examples, we have formed conventional form-factor and microbattery high power cells based on a lithiated manganese oxide cathode and carbon or NiSn anodes, and high energy cells based on a silicon anode. Time permitting, I will also describe how such engineering can also provide benefits to supercapacitor systems.